Aerosol particles
Table of Contents
Aerosol is a system of solid or liquid particles suspended by a mixture of gases. The
term aerosols covers a wide spectrum of small particles, like sea salt particles,
mineral dust, pollen, drops of sulphuric acid and many others. Aerosols have a great
impact on several atmospheric phenomena, Earth’s climate and on biosphere. During their
atmospheric residence, different size solid and liquid particles influence the radiation
and energy budget of the Earth’s, the hydrological cycle, atmospheric circulation and
the abundance of trace gases. Aerosol particles can be characterized by their
concentration, size distribution, structure and chemical composition, which are highly
variable both temporally and spatially.
After the emission of aerosol particles, they undergo various physical and
chemical processes. During these processes, size, composition and structure of
particles can be changed. Finally, they can be removed from the atmosphere to the
surfaces by dry or wet deposition processes (Figure 9.1).
Aerosols originate from a wide variety of natural and anthropogenic sources.
Various aerosol particles are generated through a combination of physical,
chemical and biological processes. Based on the formation processes, different
source types can be distinguished. Primary particles emitted directly to the
atmosphere as liquids or solids, through a wide range of processes
(Bulk-to-Particle Conversion, BPC). Some particles formed by nucleation[18] and condensation[19] of precursor gases (Gas-To-Particle Conversation, GPC), and others
from the reactions of dissolved substance in cloud droplets.
During Bulk-to-Particle Conversion, many different aerosol particles are generated from solid or liquid base materials. Oceans and dry continental regions are the two main natural sources of atmospheric aerosol. A large amount of water droplets and sea salts are released to the atmosphere through sea spray and air bubbles at the surface of the seas (Figure 9.2).
As a water droplet evaporates, the salt is left suspended into the atmosphere forming a maritime aerosol particle (e.g. sodium-chloride (NaCl), magnesium sulphate (MgSO4)). Other major source of primary particles is the windblown mineral dust from dry continental area, like deserts and semi arid regions. Further natural sources are volcanic ash, clay particles from soil erosion and biological materials (plant debris, pollen etc.). Additionally, different particles are formed by anthropogenic activities, like biomass burning, combustion of fossil fuel or industrial activities (Table 9.1).
Aerosol particles originated during Gas-To-Particle Conversion (e.g., sulphates, secondary organics) are not directly emitted, but are formed in the atmosphere from gaseous precursors (Table 9.2). Two basic processes can cause the formation of these secondary particles: an existing particle may grow through material condensing from gas phase, or new particle may forms through homogeneous nucleation.
Some other particles can form or transform by cloud droplets. When a cloud condensation nucleus[20] as an aerosol particle dissolves in the water, and then reacts with other substances, it can build new aerosol substance and form a new aerosol particle when the water evaporates.
Table 9.1: Primary particle emissions (Tg / year) Source: IPCC (2001)
Table 9.2: Annual source strength for present day emissions of aerosol
precursors (Tg N, S or C /year). Source: IPCC (2001)
During Bulk-to-Particle Conversion, many different aerosol particles are generated from solid or liquid base materials. Oceans and dry continental regions are the two main natural sources of atmospheric aerosol. A large amount of water droplets and sea salts are released to the atmosphere through sea spray and air bubbles at the surface of the seas (Figure 9.2).
As a water droplet evaporates, the salt is left suspended into the atmosphere forming a maritime aerosol particle (e.g. sodium-chloride (NaCl), magnesium sulphate (MgSO4)). Other major source of primary particles is the windblown mineral dust from dry continental area, like deserts and semi arid regions. Further natural sources are volcanic ash, clay particles from soil erosion and biological materials (plant debris, pollen etc.). Additionally, different particles are formed by anthropogenic activities, like biomass burning, combustion of fossil fuel or industrial activities (Table 9.1).
Aerosol particles originated during Gas-To-Particle Conversion (e.g., sulphates, secondary organics) are not directly emitted, but are formed in the atmosphere from gaseous precursors (Table 9.2). Two basic processes can cause the formation of these secondary particles: an existing particle may grow through material condensing from gas phase, or new particle may forms through homogeneous nucleation.
Some other particles can form or transform by cloud droplets. When a cloud condensation nucleus[20] as an aerosol particle dissolves in the water, and then reacts with other substances, it can build new aerosol substance and form a new aerosol particle when the water evaporates.
Table 9.1: Primary particle emissions (Tg / year) Source: IPCC (2001)
Sources |
Range |
Carbonaceous aerosols |
66 – 217 |
Organic Matter: |
|
Biomass burning |
45 – 80 |
Fossil fuel |
10 – 30 |
Biogenic |
0 – 90 |
Black carbon: |
|
Biomass burning |
5 – 9 |
Fossil fuel |
6 – 8 |
Aircraft |
0.006 |
Industrial dust |
40 – 130 |
Sea salt |
1000 – 6000 |
Mineral (soil) dust |
1000 – 3000 |
Sources |
Range |
NOx (Tg N
y–1) |
28 – 58 |
Fossil fuel |
21.0 |
Aircraft |
0.4 – 0.9 |
Biomass burning |
2 – 12 |
Agricultural soil |
0 – 4 |
Natural soil |
3 – 8 |
Lightning |
2 – 12 |
NH3 (Tg N
y–1) |
40 – 70 |
Domestic animals |
10 – 30 |
Agriculture |
6 – 18 |
Human |
1.3 – 6.9 |
Biomass burning |
3 – 8 |
Fossil fuel and industry |
0.1 – 0.5 |
Natural soils |
1 – 10 |
Wild animals |
0 – 1 |
Oceans |
3 – 16 |
SO2 (Tg S
y–1) |
67 – 130 |
Fossil fuel and industry |
60 – 100 |
Aircraft |
0.03 – 1.0 |
Biomass burning |
1 – 6 |
Volcanoes |
6 – 20 |
DMS and H2S (Tg S
y–1) |
12 – 42 |
Oceans |
13 – 36 |
Land biota and soils |
0.4 – 5.6 |
Volatile organic emissions (Tg C
y–1) |
100 – 560 |
Anthropogenic |
60 – 160 |
Terpenes |
40 – 400 |
Aerosols can be removed from the atmosphere by different ways in the function
of their size and disposition. Two main types of removing processes of aerosol
particles are wet and dry deposition (see e.g. Sportisse, 2007; Petroff et al.,
2008). In an annual global mean, about 80–90% of aerosol particles are removed
from the atmosphere by in-cloud and below-cloud scavenging (wet deposition).
Remaining part of particles is removed by different ways of dry deposition.
Wet deposition processes (the main sink of atmospheric aerosol particles):
Rain-out and washout: a part of cloud droplets form precipitation which reaches Earth’s surface removing aerosols from cloud and from the column of air below the cloud.
Cloud deposition: deposition form of aerosols in high elevation ecosystems due to interception of cloud droplets by vegetation.
Dry deposition processes (less important on a global scale):
Wet deposition processes (the main sink of atmospheric aerosol particles):
Rain-out and washout: a part of cloud droplets form precipitation which reaches Earth’s surface removing aerosols from cloud and from the column of air below the cloud.
Cloud deposition: deposition form of aerosols in high elevation ecosystems due to interception of cloud droplets by vegetation.
Dry deposition processes (less important on a global scale):
- Turbulent diffusion: for larger particles (with a diameter larger than 1 µm) eddy diffusivity becomes important.
- Gravitational settling (sedimentation): larger particles are influenced more by gravity and fall back to the surface. This process becomes increasingly important for particle sizes above 1 µm.
- Impaction: if a particle cannot follow the flow streamline around an obstacle (e.g. a larger particle), small particle can hit this obstacle (Figure 9.3).
- Interception: if an object is not directly in the path of particle moving in the gas stream (as in case of impaction), but particle approaches the edge of the obstacles, it may collected by the obstacle (Figure 9.4).
- Brownian diffusion: randomly moving smaller particles bump each other (thermal coagulation[21]) or to a larger obstacles (Figure 9.5). This process dominates for particle sizes below 0.2 µm. Brownian diffusion coefficients increase as particle diameter decreases. Additionally, in a very thin (about 1 mm) layer over the surface, the Brownian diffusion becomes more important for larger particles too.
[18] Nucleation: generally defined as creation of molecular embryos or
clusters prior to formation of a new phase during the transformation of
vapor → liquid → solid. Nucleation can occur within the original phase
(homogeneous nucleation), or on another phase, e.g. on a small particles
(heterogeneous nucleation).
[19] Condensation: gas to liquid phase change.
[20] Cloud condensation nuclei (CCN): hygroscopic aerosol particles that
can serve as nuclei of atmospheric cloud droplets, that is, particles on
which water vapour condenses.
[21] Particle coagulation: a process, in which small particles
collide with each other and coalesce completely to form a larger
particle.
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