Monday, 16 September 2013

Original IDLH Value

Substance
Original IDLH
Value
Revised IDLH
Value
Acetaldehyde 10,000 ppm 2,000 ppm
Acetic acid 1,000 ppm 50 ppm
1,000 ppm 200 ppm
Acetone 20,000 ppm 2,500 ppm [LEL]
Acetonitrile 4,000 ppm 500 ppm
10 ppm 8 ppm
Acrolein 5 ppm 2 ppm
Acrylamide Unknown 60 mg/m3
Acrylonitrile 500 ppm 85 ppm
Aldrin 100 mg/m3 25 mg/m3
Allyl alcohol 150 ppm 20 ppm
Allyl chloride 300 ppm 250 ppm
270 ppm 50 ppm
2 Aminopyridine 5 ppm 5 ppm [Unch]
Ammonia 500 ppm 300 ppm
5,000 mg/m3 1,500 mg/m3
n-Amyl acetate 4,000 ppm 1,000 ppm
9,000 ppm 1,000 ppm
Aniline 100 ppm 100 ppm [Unch]
o-Anisidine 50 mg/m3 50 mg/m3 [Unch]
p-Anisidine 50 mg/m3 50 mg/m3 [Unch]
80 mg Sb/m3 50 mg Sb/m3
ANTU 100 mg/m3
100 mg/m3 [Unch]
100 mg As/m3 5 mg As/m3
Arsine 6 ppm 3 ppm
Azinphosmethyl 20 mg/m3 10 mg/m3
1,100 mg Ba/m3 50 mg Ba/m3
Benzene 3,000 ppm 500 ppm
7,000 mg/m3 1,500 mg/m3
Benzyl chloride 10 ppm 10 ppm [Unch]
10 mg Be/m3 4 mg Be/m3
Boron oxide N.E. 2,000 mg/m3
100 ppm 25 ppm
Bromine 10 ppm 3 ppm
Bromoform Unknown 850 ppm
1,3-Butadiene
20,000 ppm [LEL]
2,000 ppm [LEL]
2-Butanone 3,000 ppm
3,000 ppm [Unch]
2-Butoxyethanol 700 ppm 700 ppm [Unch]
n-Butyl acetate 10,000 ppm 1,700 ppm [LEL]
10,000 ppm 1,700 ppm [LEL]
10,000 ppm 1,500 ppm [LEL]
n-Butyl alcohol 8,000 ppm 1,400 ppm [LEL]
10,000 ppm 2,000 ppm
8,000 ppm 1,600 ppm
n-Butylamine 2,000 ppm 300 ppm
30 mg/m3 (as CrO3)
15 mg Cr(VI)/m3
3,500 ppm 250 ppm
2,500 ppm 500 ppm
1,000 ppm 100 ppm
50 mg Cd/m3 9 mg Cd/m3
9 mg Cd/m3
9 mg Cd/m3[Unc h]
100 mg As/m3 5 mg As/m3
Calcium oxide Unknown 25 mg/m3
200 mg/m3
200 mg/m3 [Unch]
Carbaryl 600 mg/m3 100 mg/m3
Carbon black N.E. 1,750 mg/m3
Carbon dioxide 50,000 ppm 40,000 ppm
500 ppm 500 ppm [Unch]
Carbon monoxide 1,500 ppm 1,200 ppm
300 ppm 200 ppm
Chlordane 500 mg/m3 100 mg/m3
200 mg/m3
200 mg/m3 [Unch]
Unknown 5 mg/m3
Chlorine 30 ppm 10 ppm
10 ppm 5 ppm
20 ppm 20 ppm [Unch]
100 ppm 45 ppm
100 mg/m3 15 mg/m3
Chlorobenzene 2,400 ppm 1,000 ppm
2 mg/m3 2 mg/m3 [Unch]
5,000 ppm 2,000 ppm
10 mg/m3 5 mg/m3
5 mg/m3 5 mg/m3 [Unch]
Chloroform 1,000 ppm 500 ppm
2,000 ppm 100 ppm
Chloropicrin 4 ppm 2 ppm
400 ppm 300 ppm
30 mg/m3 (as CrO3)
15 mg Cr(VI)/m3
N.E.
250 mg Cr(II)/m3
N.E.
25 mg Cr(III)/m3
N.E. 250 mg Cr/m3
700 mg/m3 80 mg/m3
20 mg Co/m3
20 mg Co/m3 [Unch]
N.E. 100 mg Cu/m3
N.E. 100 mg Cu/m3
N.E. 100 mg/m3
5,000 mg/m3 500 mg/m3
250 ppm 250 ppm [Unch]
Crotonaldehyde 400 ppm 50 ppm
Cumene 8,000 ppm 900 ppm [LEL]
50 mg/m3 (as CN)
25 mg/m3 (as CN)
Cyclohexane 10,000 ppm 1,300 ppm [LEL]
Cyclohexanol 3,500 ppm 400 ppm
Cyclohexanone 5,000 ppm 700 ppm
Cyclohexene 10,000 ppm 2,000 ppm
Cyclopentadiene 2,000 ppm 750 ppm
2,4-D 500 mg/m3 100 mg/m3
DDT N.E. 500 mg/m3
Decaborane 100 mg/m3 15 mg/m3
Demeton 20 mg/m3 10 mg/m3
2,100 ppm 1,800 ppm [LEL]
Diazomethane 2 ppm 2 ppm [Unch]
Diborane 40 ppm 15 ppm
125 ppm 30 ppm
9,300 mg/m3 4,000 mg/m3
1,000 ppm 200 ppm
1,000 ppm 150 ppm
50,000 ppm 15,000 ppm
Unknown 5 mg/m3
4,000 ppm 3,000 ppm
4,000 ppm 1,000 ppm
250 ppm 100 ppm
50,000 ppm 5,000 ppm
150 ppm 25 ppm
50,000 ppm 15,000 ppm
Dichlorvos 200 mg/m3 100 mg/m3
Dieldrin 450 mg/m3 50 mg/m3
Diethylamine 2,000 ppm 200 ppm
500 ppm 100 ppm
2,500 ppm 2,000 ppm
25 ppm 10 ppm
2,000 ppm 500 ppm
1,000 ppm 200 ppm
400 ppm 300 ppm
Dimethylamine 2,000 ppm 500 ppm
100 ppm 100 ppm [Unch]
1,800 mg/m3 200 mg/m3
3,500 ppm 500 ppm
50 ppm 15 ppm
9,300 mg/m3 2,000 mg/m3
10 ppm 7 ppm
200 mg/m3 50 mg/m3
Dinitroocresol 5 mg/m3 5 mg/m3 [Unch]
Dinitrotoluene 200 mg/m3 50 mg/m3
Unknown 5,000 mg/m3
Dioxane 2,000 ppm 500 ppm
Diphenyl 300 mg/m3 100 mg/m3
Unknown 600 ppm
Endrin 2,000 mg/m3 2 mg/m3
Epichlorohydrin 250 ppm 75 ppm
EPN 50 mg/m3 5 mg/m3
Ethanolamine 1,000 ppm 30 ppm
2-Ethoxyethanol 6,000 ppm 500 ppm
2,500 ppm 500 ppm
Ethyl acetate 10,000 ppm 2,000 ppm [LEL]
Ethyl acrylate 2,000 ppm 300 ppm
Ethyl alcohol 15,000 ppm 3,300 ppm [LEL]
Ethylamine 4,000 ppm 600 ppm
Ethyl benzene 2,000 ppm 800 ppm [LEL]
Ethyl bromide 3,500 ppm 2,000 ppm
3,000 ppm 1,000 ppm
Ethyl chloride 20,000 ppm 3,800 ppm [LEL]
10 ppm 7 ppm
Ethylenediamine 2,000 ppm 1,000 ppm
400 ppm 100 ppm
1,000 ppm 50 ppm
500 mg/m3 75 mg/m3
Ethyleneimine 100 ppm 100 ppm [Unch]
Ethylene oxide 800 ppm 800 ppm [Unch]
Ethyl ether
19,000 ppm [LEL]
1,900 ppm [LEL]
Ethyl formate 8,000 ppm 1,500 ppm
Ethyl mercaptan 2,500 ppm 500 ppm
2,000 ppm 100 ppm
Ethyl silicate 1,000 ppm 700 ppm
Ferbam N.E. 800 mg/m3
N.E. 500 mg/m3
500 mg F/m3 250 mg F/m3
Fluorine 25 ppm 25 ppm [Unch]
10,000 ppm 2,000 ppm
Formaldehyde 30 ppm 20 ppm
Formic acid 30 ppm 30 ppm [Unch]
Furfural 250 ppm 100 ppm
250 ppm 75 ppm
Glycidol 500 ppm 150 ppm
N.E. 1,250 mg/m3
Unknown 50 mg Hf/m3
Heptachlor 700 mg/m3 35 mg/m3
n-Heptane 5,000 ppm 750 ppm
300 ppm 300 ppm [Unch]
2 mg/m3 2 mg/m3 [Unch]
n-Hexane 5,000 ppm 1,100 ppm [LEL]
2-Hexanone 5,000 ppm 1,600 ppm
Hexone 3,000 ppm 500 ppm
4,000 ppm 500 ppm
Hydrazine 80 ppm 50 ppm
50 ppm 30 ppm
100 ppm 50 ppm
50 ppm 50 ppm [Unch]
30 ppm 30 ppm [Unch]
75 ppm 75 ppm [Unch]
2 ppm 1 ppm
300 ppm 100 ppm
Hydroquinone Unknown 50 mg/m3
Iodine 10 ppm 2 ppm
N.E. 2,500 mg Fe/m3
Isoamyl acetate 3,000 ppm 1,000 ppm
10,000 ppm 500 ppm
7,500 ppm 1,300 ppm [LEL]
8,000 ppm 1,600 ppm
Isophorone 800 ppm 200 ppm
16,000 ppm 1,800 ppm
12,000 ppm 2,000 ppm [LEL]
Isopropylamine 4,000 ppm 750 ppm
Isopropyl ether 10,000 ppm 1,400 ppm [LEL]
1,000 ppm 400 ppm
Ketene Unknown 5 ppm
700 mg Pb/m3 100 mg Pb/m3
Lindane 1,000 mg/m3 50 mg/m3
Lithium hydride 55 mg/m3 0.5 mg/m3
L.P.G.
19,000 ppm [LEL]
2,000 ppm [LEL]
N.E. 750 mg/m3
Malathion 5,000 mg/m3 250 mg/m3
Unknown 10 mg/m3
N.E. 500 mg Mn/m3
28 mg Hg/m3 10 mg Hg/m3
10 mg Hg/m3 2 mg Hg/m3
Mesityl oxide 5,000 ppm 1,400 ppm [LEL]
Methoxychlor N.E. 5,000 mg/m3
Methyl acetate 10,000 ppm 3,100 ppm [LEL]
15,000 ppm [LEL]
1,700 ppm [LEL]
15,000 ppm 3,400 ppm [LEL]
Methyl acrylate 1,000 ppm 250 ppm
Methylal
15,000 ppm [LEL]
2,200 ppm [LEL]
Methyl alcohol 25,000 ppm 6,000 ppm
Methylamine 100 ppm 100 ppm [Unch]
4,000 ppm 800 ppm
Methyl bromide 2,000 ppm 250 ppm
2,000 ppm 200 ppm
4,000 ppm 200 ppm
Methyl chloride 10,000 ppm 2,000 ppm
1,000 ppm 700 ppm
10,000 ppm 1,200 ppm [LEL]
10,000 ppm 500 ppm
2,500 ppm 600 ppm
100 mg/m3 75 mg/m3
5,000 ppm 2,300 ppm
Methyl formate 5,000 ppm 4,500 ppm
3,000 ppm 100 ppm
50 ppm 20 ppm
Methyl iodide 800 ppm 100 ppm
2,000 ppm 400 ppm
20 ppm 3 ppm
400 ppm 150 ppm
4,000 ppm 1,000 ppm
Methyl styrene 5,000 ppm 700 ppm
Mica N.E. 1,500 mg/m3
N.E. 5,000 mg Mo/m3
N.E. 1,000 mg Mo/m3
100 ppm 100 ppm [Unch]
Morpholine 8,000 ppm 1,400 ppm [LEL]
10,000 ppm [LEL]
1,000 ppm [LEL]
Naphthalene 500 ppm 250 ppm
7 ppm 2 ppm
N.E. 10 mg Ni/m3
Nicotine 35 mg/m3 5 mg/m3
Nitric acid 100 ppm 25 ppm
Nitric oxide 100 ppm 100 ppm [Unch]
p-Nitroaniline 300 mg/m3
300 mg/m3 [Unch]
Nitrobenzene 200 ppm 200 ppm [Unch]
1,000 mg/m3 100 mg/m3
Nitroethane 1,000 ppm
1,000 ppm [Unch]
50 ppm 20 ppm
2,000 ppm 1,000 ppm
Nitroglycerine 500 mg/m3 75 mg/m3
Nitromethane 1,000 ppm 750 ppm
1-Nitropropane 2,300 ppm 1,000 ppm
2-Nitropropane 2,300 ppm 100 ppm
200 ppm 200 ppm [Unch]
Unknown Unknown [Unch]
Octane 5,000 ppm 1,000 ppm [LEL]
N.E. 2,500 mg/m3
1 mg Os/m3
1 mg Os/m3 [Unch]
Oxalic acid 500 mg/m3
500 mg/m3 [Unch]
0.5 ppm 0.5 ppm [Unch]
Ozone 10 ppm 5 ppm
Paraquat 1.5 mg/m3 1 mg/m3
Parathion 20 mg/m3 10 mg/m3
Pentaborane 3 ppm 1 ppm
Unknown Unknown [Unch]
150 mg/m3 2.5 mg/m3
n-Pentane
15,000 ppm [LEL]
1,500 ppm [LEL]
2-Pentanone 5,000 ppm 1,500 ppm
10 ppm 10 ppm [Unch]
385 ppm 100 ppm
10,000 ppm 1,100 ppm [LEL]
Phenol 250 ppm 250 ppm [Unch]
Unknown 25 mg/m3
N.E. 100 ppm
N.E. 10 ppm
Unknown 100 ppm
Phenylhydrazine 295 ppm 15 ppm
Phosdrin 4 ppm 4 ppm [Unch]
Phosgene 2 ppm 2 ppm [Unch]
Phosphine 200 ppm 50 ppm
Phosphoric acid 10,000 mg/m3 1,000 mg/m3
N.E. 5 mg/m3
200 mg/m3 70 mg/m3
750 mg/m3 250 mg/m3
50 ppm 25 ppm
10,000 mg/m3 60 mg/m3
Picric acid 100 mg/m3 75 mg/m3
Pindone 200 mg/m3 100 mg/m3
N.E. 4 mg Pt/m3
Portland cement N.E. 5,000 mg/m3
Propane
20,000 ppm [LEL]
2,100 ppm [LEL]
8,000 ppm 1,700 ppm
4,000 ppm 800 ppm
2,000 ppm 400 ppm
Propylene imine 500 ppm 100 ppm
Propylene oxide 2,000 ppm 400 ppm
2,000 ppm 500 ppm
Pyrethrum 5,000 mg/m3
5,000 mg/m3 [Unch]
Pyridine 3,600 ppm 1,000 ppm
Quinone 300 mg/m3 100 mg/m3
N.E. 100 mg Rh/m3
N.E. 2 mg Rh/m3
Ronnel 5,000 mg/m3 300 mg/m3
Rotenone Unknown 2,500 mg/m3
Unknown 1 mg Se/m3
5 ppm 2 ppm
N.E. 3,000 mg/m3
Silica, crystalline (respirable dust)
N.E.
cristobalite/tridymite:
25 mg/m3
quartz/tripoli:
50 mg/m3
N.E. 10 mg Ag/m3
Soapstone N.E. 3,000 mg/m3
5 mg/m3 2.5 mg/m3
250 mg/m3 10 mg/m3
Stibine 40 ppm 5 ppm
29,500 mg/m3 20,000 mg/m3
Strychnine 3 mg/m3 3 mg/m3 [Unch]
Styrene 5,000 ppm 700 ppm
Sulfur dioxide 100 ppm 100 ppm [Unch]
Sulfuric acid 80 mg/m3 15 mg/m3
10 ppm 5 ppm
1 ppm 1 ppm [Unch]
1,000 ppm 200 ppm
2,4,5-T Unknown 250 mg/m3
Talc N.E. 1,000 mg/m3
N.E. 2,500 mg Ta/m3
TEDP 35 mg/m3 10 mg/m3
N.E. 25 mg Te/m3
1 ppm 1 ppm [Unch]
TEPP 10 mg/m3 5 mg/m3
Unknown 500 mg/m3
15,000 ppm 2,000 ppm
15,000 ppm 2,000 ppm
150 ppm 100 ppm
500 ppm 150 ppm
Unknown Unknown [Unch]
40 mg Pb/m3
40 mg Pb/m3 [Unch]
Tetrahydrofuran
20,000 ppm [LEL]
2,000 ppm [LEL]
40 mg Pb/m3
40 mg Pb/m3 [Unch]
5 ppm 5 ppm [Unch]
5 ppm 4 ppm
Tetryl N.E. 750 mg/m3
20 mg Tl/m3 15 mg Tl/m3
Thiram 1,500 mg/m3 100 mg/m3
400 mg Sn/m3 100 mg Sn/m3
Unknown 25 mg Sn/m3
N.E. 5,000 mg/m3
Toluene 2,000 ppm 500 ppm
10 ppm 2.5 ppm
o-Toluidine 100 ppm 50 ppm
125 ppm 30 ppm
500 ppm 100 ppm
1,000 ppm
1,000 ppm [Unch]
Unknown Unknown [Unch]
1,000 ppm 100 ppm
4,500 ppm 2,000 ppm
Triethylamine 1,000 ppm 200 ppm
50,000 ppm 40,000 ppm
1,000 mg/m3 500 mg/m3
40 mg/m3 40 mg/m3 [Unch]
N.E. 1,000 mg/m3
Turpentine 1,500 ppm 800 ppm
30 mg U/m3 10 mg U/m3
20 mg U/m3 10 mg U/m3
Vanadium dust
70 mg/m3 (as V2O5)
35 mg V/m3
Vanadium fume
70 mg/m3 (as V2O5)
35 mg V/m3
Vinyl toluene 5,000 ppm 400 ppm
Warfarin 350 mg/m3 100 mg/m3
1,000 ppm 900 ppm
Xylidine 150 ppm 50 ppm
N.E. 500 mg Y/m3
4,800 mg/m3 50 mg/m3
Zinc oxide 2,500 mg/m3 500 mg/m3
500 mg Zr/m3 25 mg Zr/m3

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