"Hazardous Chemical" means any chemical
which is of the criteria specified in part I of Schedule I and is included in the list of column (2) of part
II of that Schedule, or any chemical included in the list in Column 2 of Schedule 2; or any chemical
included in the list of Column 2 of Schedule 3; and. "Industrial activity" means any operation or process
carried out in an industrial installation referred to in Schedule 4 involving or likely to
involve one or more hazardous chemicals and includes on site storage or on-site
transport which is associated with that operation or process as the case may be;
or isolated storage and
"Isolated Storage" means storage where no
other manufacturing process than pumping of hazardous chemical is carried out
and that storage involves at least the quantity of that chemical set out in Schedule 2, but does not include
storage associated with an installation specified in schedule 4 on the same
site;
SCHEDULE I
(SEE RULE 68 –
j(1)(a)(i), (2)(1), (3)(1)(a)
INDICATIVE CRITERIA AND LIST OF CHEMICALS
PART I - INDICATIVE CRITERIA
INDICATIVE CRITERIA AND LIST OF CHEMICALS
PART I - INDICATIVE CRITERIA
(a) Toxic Chemicals:
Chemicals having the following values of acute toxicity and which owing to their physical and chemical properties, are capable of producing major accident hazards:
Chemicals having the following values of acute toxicity and which owing to their physical and chemical properties, are capable of producing major accident hazards:
Sr.No.
|
Degree of toxicity
|
LD50 Absorbed orally in rats mg/kg body weight
|
||
Sr.No.
Degree of Medium lethal Medium lethal Medium
Toxicity dose by the dose by the lethal
oral route dermal route concentr-
toxicity) (dermal LD50 ation by
LD50 (mg/kg body weight inhalation
body weight of test route(Four
of test ani- animals) hours)LC50
mals) (mg/1 inh-
alation in
test ani-
mals)
___________________________________________________________
1. Extremely 1-50 1-200 0.1 - 0.5
toxic
2. Highly 51-500 201-2000 0.5 - 2.0
toxic
__________________________________________________________
Toxicity dose by the dose by the lethal
oral route dermal route concentr-
toxicity) (dermal LD50 ation by
LD50 (mg/kg body weight inhalation
body weight of test route(Four
of test ani- animals) hours)LC50
mals) (mg/1 inh-
alation in
test ani-
mals)
___________________________________________________________
1. Extremely 1-50 1-200 0.1 - 0.5
toxic
2. Highly 51-500 201-2000 0.5 - 2.0
toxic
__________________________________________________________
1.
Flammable Chemicals:
1.
flammable gases ; chemicals which in the gascous state at normal
pressure and mixed with air become flammable and the boiling point of which at
normal pressure is 20 C or below;
2.
Highly flammable liquids; chemicals which have a flash point
lower than 23 C and the boiling point of which at normal pressure is above 20
C;
3.
flammable liquids: chemicals which have a flash point lower than
65 C and which remain liquids under pressure, where particular processing
conditions, such as high pressure and high temperature, may create major
accident hazards.
2.
Explosives: chemicals which may explode under the
effect of flame, heat or photo-chemical conditions or which are more sensitive
to shocks or friction than dinitrobenzene.
PART II LIST OF HAZARDOUS AND TOXIC CHEMICALS
Sl.No. Name of the Chemical
1. 2.
1. Acetone
2. Acetone Cyanohydrine
3. Acetyl Chloride
4. Acetylene (Ethyne)
5. Acrolein (2-Propenal)
6. Acrylonitrile
7. Aldicarb
8. Aldrin
9. Alkyl Phthalate
10. Allyl Alcohol
11. Allylamine
12. Alpha Naphthyl Thiourea (Autu)
13. Aminodiphenyl, -4
14. Aminophenol-2
15. Amiton
16. Ammonia
17. Ammonium Nitrate
18. Ammonium Nitrates in fertilizers
19. Ammonium Sulfamate
20. Anabasine
21. Aniline
22. Anisidine-p
23. Antimony and Compounds
24. Antimony Hydride (Stibine)
25. Arsenic Hydride (Arsine)
26. Arsenic Pentoxide, (Arsenic)(v) Acid and Salts
27. Arsenic Trioxide, Arsenious (iii) Acids and Salts
28. Asbestos
29. Azinphos-Ethyl
30. Azinphos-Methyl
31. Barium Azide
32. Benzene
33. Benzidine
34. Benzidine Salts
35. Benzoquinone
36. Benzoyl Chloride
37. Benzoyl Peroxide
38. Benzyl Chloride
39. Benzyl Cyanide
40. Beryllium (Powders, Compunds)
41. Biphenyl
42. Bis (2-Chloromethyl) Ketone
43. Bis (2, 4, 6-Trinitrophenyl) Amine
44. Bis (2-Chloroethyl) Sulphide
45. Bis (Chloromethyl) ketone
46. Bis (tert-Butylperoxy) Butane, -2, 2
47. Bis (tert-Butylperoxy) Cyclohexane, 11,
48. Bis, 1, 2 Tribromophenoxy-Ethane
49. Bisphenol
50. Boron and Compunds
51. Bromine
52. Bromine Pentafluoride
53. Bromoform
54. Butadiene-1, 3
55. Butane
57. Butanone-2
58. Butoxy Ethanol
59. ButylGlycidal Ether
60. Butyl Peroxyacetate, tert
61. Butyl peroxyisobutyrate, tert
62. Butyl peroxy isopropye carbonate, tert
63. Butyl Peroxymaleate, tert
64. Butyl Peroxypivalate, -tert
65. Butyl vinyl Ether
66. Butyl-n-Mercaptan
67. Butylamine
68. C 9-Aromatic Hydrocarbon Fraction
69. Cadmium and Compounds
70. Cadmium Oxide (fumes)
71. Calcium Cyanide
72. Captan
73. Captofol
74. Carbaryl (Sevin)
75. Carbofuran
76. Carbon Disulphide
77. Carbon Monoxide
78. Carbon Tetrachloride
79. Carbophenothion
80. Cellulose Nitrate
81. Chlorates (used in explosives)
82. Chlordane
83. Chlorfenvinphos
84. Chlorinated Benzenes
85. Chlorine
86. Chlorine Dioxide
87. Chlorine Oxide
88. Chlorine Trifluoride
89. Chlormequat Chloride
90. Chloroacetal Chloride
91. Chloroacetaldehyde
92. Chloroaniline, -2
93. Chloroaniline, -4
94. Chlorobenzene
95. Chlorodiphenyl
96. Chloroepoxypropane
97. Chloroethanol
98. Chloroethyl Chloroformate
99. Chlorofluorocarbons
100. Chloroform
101. Chloroformyl, -4, Morpholine
102. Chloromethane
103. Chloromethyl Ether
104. Chloromethyl Methyl Ether
105. Chloronitrobenzene
106. Chloroprene
107. Chlorosulphonic Acid
108. Chlorotrinitrobenzene
109. Chloroxuron
110. Chromium and Compounds
111. Cobalt and Compounds
112. Copper and Compounds
113. Coumafuryl
114. Comaphos
115. Coumatetralyl
116. Cresols
117. Crimidine
118. Cumene
119. Cyanophos
120. Cyanothoate
121. Cyanuric Fluoride
122. Cyclohexane
123. Cyclohexanol
124. Cyclohexanone
125. Cycloheximide
126. Cyclopentadiene
127. Cyclopentane
128. Cyclotetramethylentetranitramine
129. Cyclotrimethylene Trinitramine
130. DDT
131. Decabromodiphenyl Oxide
132. Demeton
133. Di-Isobutyl Peroxide
134. Di-n-propyl Peroxydicarbonate
135. Di-sec-Butyl Peroxydicarbonate
136. Dialifos
137. Diazodinitrophenol
138. Diazomethane
139. Dibenzyl Peroxydicarbonate
140. Dichloroacetylene-O
141. Dichloroobenzene-O
142. Dichlorobenzene-P
143. Dichloroethane
144. Dichloroethyl Ether
145. Dichlorophenol, -2, 4
146. Dichlorophenol, -2, 6
147. Dichlorophenoxy Acetic Acid, -2, 4(2, 4-D)
148. Dichloropropane, -1,2
149. Dichlorosalicylic Acid, -3, 5
150. Dichlorvos (DDVP)
151. Dicrotophos
152. Dieldrin
153. Diepoxybutane
154. Diethyl Peroxydicarbonate
155. Diethylene Glycol Dinitrate
156. Diethylene Triamine
157. Diethyleneglycol Butyl Ether/Diethyleneglycol
Butyl Acetate
158. Diethylenetriamine (DETA)
159. Diglycidyl Either
160. Dithydroperoxypropane, -2, 2
161. Di-isobutyryl Peroxide
162. Dimefox
163. Dimethoate
164. Dimethyl Phosphoramidocyanidic Acid
165. Dimethyl Phthalate
166. Dimethylcarbomyl
167. Dimethylnitrosamine
168. Dinitrophenol, Salts
169. Dinitrotoluene
170. Dintro-o-Cresol
171. Dioxane
172. Dioxathion
173. Dioxolane
174. Diphacinone
175. Diphosphoramide Octamethyl
176. Dipropylene Glycolmethylether
177. Disulfoton
178. Endosulfan
179. Endrin
180. Epichlorohydrine
181. EPN
182. Epoxypropane, 1, 2
183. Ethion
184. Ethyl Carbamate
185. Ethyl Ether
186. Ethyl Hexanol,-2
187. Ethyl Mercaptan
188. Ethyl Methacrylate
189. Ethyl Nitrate
190. Ethylamine
191. Ethylene
192. Ethylene Chlorohydrine
193. Ethylene Diamine
194. Ethylene Dibromide
195. Ethylene Dichloride
196. Ethylene Glycol Dinitrate
197. Ethylene Oxide
198. Ethyleneimine
199. Ethylthiocyanate
200. Fensulphothion
201. Fluenetil
202. Fluoro,-4, -2-Hydroxybutyrix Acid and Salts
Esters, Amides
203. Fluoracetic Acid and Salts, Esters, Amides
204. Fluorobutyric Acid, -4, and Salts,
Esters, Amides
205. Fluorocortonic Acid, -4, Salts, Esters,
Amides
206. Formaldehyde
207. Glyconitrile (Hydroxyacetonitrile)
208. Guanyl,-1, -4-Nitrosaminoguanyl-1-Tetrazene
209. Heptachlor
210. Hexachloro Cyclopentadiene
211. Hexachlorocyclohexane
212. Hexachlorocyclomethane
213. Hexachlorodibenzo-p-Dioxin, 1,2,3,7,8,9
214. Hexafluoropropene
215. Hexamethylphosphoramide
216. Hexamethyl, -3, 3, 6, 9, 9-1, 2, 4,
5-Tetraoxacyclononane
217. Hexamethylendiamine
218. Hexane
219. Hexanitrostilbene, -2, 2, 4, 4, 6, 6
220. Hexavalent Chromium
221. Hydrazine
222. Hydrazine Nitrate
223. Hydrochloric Acid
224. Hydrogen
225. Hydrogen Bromide (Hydrobromic Acid)
226. Hydrogen Chloride (Liquified Gas)
227. Hydrogen Cyanide
228. Hydrogen Fluoride
229. Hydrogen Selenide
230. Hydrogen Sulphide
231. Hydroquinone
232. Iodine
233. Isobenzan
234. Isodrin
235. Isophorone Diissocyanate
236. Isopropyl Ether
237. Juglone (5-Hydroxynaphthalene-1, 4-Dione)
238. Lead (inorganic fumes & dusts)
239. Lead 2, 4, 6-Trinitroresorcinoxide (Lead Styphnate)
240. Lead Azide
241. Leptophos
242. Lindane
243. Liquified Petroleum Gas (LPG)
244. Maleic Anhydride
245. Managanese & Compounds
246. Mercapto Benzothiazole
247. Mercury Alkyl
248. Mercury Fulminate
249. Mercury Methyl
250. Methacrylic Anhydride
251. Methacrylonitrile
252. Methacryloyl Chloride
253. Methamidophos
254. Methanesuphonyl Fluoride
255. Methanthiol
256. Methoxy Ethanol (2-Methyl Cellosolve)
257. Methoxycthylmercuric Acetate
258. Methyl Acrylate
269. Methyl Alcohol
260. Methyl Amylketone
261. Methyl Bromide (Bromomethane)
262. Methyl Chloride
263. Methyl Chloroform
264. Methyl Cyclohexene
265. Methyl ethyl Ketone Peroxide
266. Methyl Hydrazine
267. Methyl Isobutyl Ketone
268. Methyl Isobutyl Ketone Peroxide
269. Methyl Isocyanate
270. Methyl Isothiocyanate
271. Methyl Mercaptan
272. Methyl Methacrylate
273. Methyl Parathion
274. Methyl Phosphonic Dichloride
275. Mehtyl-N, 2, 4, 6-Tetranitroaniline
276. Methylene Chloride
277. Methylenebis, -4, 4, (2, -chloroanilne)
278. Methyltrichlorosilane
279. Mevinphos
280. Molybdenum & Compounds
281. N-Methyl-N, 2, 4, 6-Tetranitroanaline
282. Naphtha (Coal Tar)
283. Naphtylamine, 2
284. Nickel & Compounds
285. Nickel Tetracarbonyl
286. Nitroaniline-O
287. Nitroaniline-P
288. Nitrobenzene
289. Nitrochlorobenzene-P
290. Nitrocyclohexane
291. Nitroethane
292. Nitrogen Dioxide
293. Nitrogen Oxides
294. Nitrogen Trifluoride
295. Nitroglycerine
296. Nitrophenol-P
297. Nitropropane-1
298. Nitropropane-2
299. Nitrosodimethylamine
300. Nitrotoluene
301. Octabromophenyl Oxide
302. Oleum
303. Oleylamine
304. OO-Diethyl S-Ethysulphonlmethyl
305. OO-Diethyl S-Ethylsulphonylmethyl
Phosphorothioate
306. OO-Diethyl S-Ethylthiomethyl Phosphe rothioate
307. OO-Diethyl S-Isopropylthiomethyl
Phosphorodithioate
308. OO-Diethyl S-propylthiomethyl
Phophorodithioate
309. Oxyamyl
310. Oxydisulfoton
311. Oxygen (liquid)
312. Oxygen Difluoride
313. Ozone
314. Paroxon (diethyl 4-Nitrophenyl Phosphate)
315. Paraquat
316. Parathion
317. Parathion Methyl
318. Paris green (Bis Aceto Hexametarsen ito
Tetracopper)
319. pentaborane
320. Pentabromodiphenyl Oxide
321. Pentabromophenol
322. Pentachloro Naphthalene
323. Pentachloroethane
324. Pentachlorophenol
325. Pentaerythritol Tetranitrate
326. Pentane
327. Peracetic Acid
328. Perchloroethylene
329. Perchloromethyl Mercaptan
330. Petanone, 2, 4-Methyl
331. Phenol
332. Phenyl Glycidal Ether
333. Phenylene p-Diamine
334. Phenylmercury Acetate
335. Phorate
336. Phosacetim
337. Phosalone
338. Phosfolan
339. Phosgene (carbonyl chloride)
340. Phosmet
341. Phosphamidon
342. Phosphine (Hydrogen Phosphide)
343. Phosphoric Acid and Esters
344. Phosphoric Acid, Bromoethyl Bromo
(2, 2-Dimethylpropyl) Bromoethyl Ester
345. Phosphoric Acid, Bromoethyl Bromo
(2,2-Dimethylpropyl) Chloroethyl Ester
346. Phosphoric Acid Chloroethyl Bromo
(2,2-Dimethoxylpropyl Chloroethylester)
347. Phosphorous & Compounds
348. Phostalan
349. Picric Acid (2,4, 6-Trinitrophenol)
350. Polybrominated Biphenyls
351. Potassium Arsenite
352. Potassium Chlorate
353. Promurit (1-(3, 4-Dichlorophenyl)-
3 Triazenethiocarboxamide)
354. Propanesultone-1, 3
355. Propen-1, -2-Chloro-1, 3-Diol-Diacetate
356. Propylene Oixde
357. Propyleneimine
358. Pryazoxon
359. Selenium Hexafluoride
360. Semicarbazide Hydrochloride
361. Sodium Arsenite
362. Sodium Azide
363. Sodium Chlorate
364. Sodium Cyanide
365. Sodium Picramate
366. Sodium Selenite
367. Styrene, 1, 1, 3, 2-Tetrachloroethane
368. Sulfotep
369. Sulphur dichloride
370. Sulphur Dioxide
371. Sulphur Trioxide
372. Sulphuric Acid
373. Sulphoxide, 3-Chloropropyloctyl
374. Tellurium
375. Tellurium Hexafluoride
376. Tepp
377. Terbufos
378. Tetrabromobisphenol-A
379. Tetrachloro, 2, 2, 5,6,2, 5-Cyclohexadiene-1,
4-Dione
380. Tetrachlorodibenzo-p Dloxin, 2,3,7,8 (TCDD)
381. Tetraethyl Lead
382. Tetrafluoroethane
383. Tetramethylenedisulphotetramine
384. Tetramethyl Lead
385. Tetranitromethane
386. Thallium & Compounds
387. Thionazin
388. Thionazin
389. Thinoyl Chloride
389. Tirpate
390. Toluene
391. Toluene-2-4-Diicocyanate
392. Toluidine-O
393. Toluene 2,6-Diisocyanate
394. Trans-1, 4-Chlorobutene
395. Tri-1 (cyclohexyl) Stannyl-1H-1, 2, 4-Trazole
396. Triamino, -1, 3, 5, 2, 4, 6-Trintroxenzene
397. Tribromophenol, 2, 4, 6
398. Trichloro Acetyl Chloride
399. Trichloro Ethane
400. Trichloro Napthalene
401. Trichloro (Chloromethyl) Silane
402. Trichlorodichlorophenylsilane
403. Trichloroethane, 1,1, 1
404. Trichlorethyl Silane
405. Trichloroethylene
406. Trichloromethanesulphenyl Chloride
407. Trichlorophenol, 2, 2, 6
408. Trichloropnenol, 2, 4, 5
409. Triethylamine
410. Triethylenemelamine
411. Trimethyl Chlorosilane
412. Trimethylopropane Phosphite
413. Trinitroaniline
414. Trinitroanisole, 2, 2, 4, 6
415. Trinitrobenzene
416. Trinitrobenzoic Acid
417. Trinitrocresol
418. Trinitrophenetole, 2, 5, 6
419. Trinitroresorcinol, 2,4,6 (Styphnic Acid)
420. Trintrotoluene
421. Triothocresyl Phosphate
422. Triphenyltin Chloride
423. Turpentine
424. Uranium & Compounds
425. Vanadium & Compounds
426. Vinyl Chloride
427. Vinyl Fluoride
428. Vinyl Toluene
429. Warfarin
430. Xylene
431. Xylidine
432. Zinc & Compounds
433. Zirconium & Compounds
SCHEDULE 2
(See Rule 68-j-1(a)
(ii),1(c),3(1)(b) and (5)(1)(c) and (d), 6(1)
ISOLATED STORAGE OF INSTALLANTION OTHER THAN THOSE
COVERED BY SCHEDULE 4.
(a)
The quantities set out below relate to each
installation or group of installations belonging to the occupier where the
distance between installations is not sufficient to avoid, in foreseeable
circumstances any aggravation of major accident hazards. These quantities apply
in any case of each of the installations belonging to the same occupier where
the distance between the installation is less than 500metres.
(b)
For the purpose of determining the quantity of a
hazardous chemical at an isolated storage, account shall also be taken of any
hazardous chemical which is:
(i)
in that part of any pipeline under the control
of the occupier having control of the site, which is 500 meters of that site
and connected to it.
(ii)
at any other site under the control of the
occupier any part of the boundary of which is 500 meters of the said site, and
(iii)
in any vehicle, vessel, aircraft or hovercraft
or hovercraft under the control of the same occupier which is used for storage
purpose either at the site or within 500metres of it.
but no account shall be taken of
any hazardous chemical which is in a vehicle, vessel, aircraft or hovercraft
for transporting it.
Sr
No.
|
Chemical or group of chemicals
|
Quantity
|
(tonnes)
|
For application of sub-Rules 3.5 and 6 to 8
|
For application of Sub-Rule6
|
||
(col.1)
|
(col.2)
|
(col.3) Tonnes
|
(col.4)
|
1.
|
Acryionitrile
|
350
|
5.000
|
2.
|
Ammonia
|
60
|
600
|
3.
|
Ammonium nitrate
|
350*
|
2500*
|
4.
|
Ammonium nitrate fertilizers
|
1,250
|
10,000
|
5.
|
Chlorine
|
10
|
25
|
6.
|
Flammable gases as defined in Schedule1, paragraph 1,
paragraph (b)
|
50
|
300
|
7.
|
Highly flammable liquids as define in Schedule I
paragraph(b)
|
10,000
|
10,000
|
8.
|
Liquid oxygen
|
200
|
2000
|
9.
|
Sodium chlorate
|
25
|
250
|
10.
|
Sulphur dioxide
|
20
|
500
|
11.
|
Sulphur trioxide
|
15
|
100
|
*Where this chemical is in a state which gives it properties
capable of creating of creating a major accident hazard.
Footnotes-
(a)
This applies to ammonium nitrate and mixture of ammonium nitrate where
the nitrogen content derived from the ammonium nitrate is greater than 28 per
cent by weight and to aqueous solutions solutions of ammonium nitrate where the
concentration of ammonium nitrate is greater than 90 per cent by weight.
(b)
This applies to straight ammonium nitrate
fertilizers and to compound fertilisers where the nitrogen content derived form
the ammonium nitrate is greater than 28 per cent by weight (a compound
fertilizer contains ammonium nitrate together with phosphate and/or potash.)
SCHEDULE 3
(See Rules 68-J
1(a)(iii), 1(e) and (5)(1) and (b),6(1))
LIST OF HAZARDOUS
CHAMICALS FOR APPLICATION OF SUB-RULES
5 AND 7 TO 13
(a) The
quantities set out below relate to installation or group of installations
belonging to the same occupier where the distance between the installations is
not sufficient to avoid in foreseeable circumstances, any aggravation of major
accident hazards. These quantities apply in any case to each group of
installation belonging to the same occupier where the distance between the
installations is lass then 500 meters.
(b) For the purpose of determining the
quantity of control of a hazardous chemical in an industrial installation,
account shall also be taken of any hazardous chemical which is:
(i)
in that part of any pipeline under the control of the
occupier having control of the site, which is within 500 meters of that site
and connected to it;
(ii)
at any other site under the control of the same
occupier any part of the boundary of which is within 500 meters of side; and
(iii)
in any vehicle, vessel, aircraft or hovercraft under
the control of the same occupier which is used for storage purpose either at
the site or within 500 meters of it.
But no account shall be taken of
any hazardous chemical which is in a vehicle vessel, aircraft or hovercraft
used for transporting it.
SCHEDULES
3 (Continued)
PART 1 – NAMED CHAMICALS
Sr. No. Chemical Quantity CAS Number
____________________
For For
Application application
Of
sub-rules of sub-rules
(4)
(6) to (8) 9 to 11
and
12
(1) (2) (3) (4) (5)
Group
1 – Toxic Chemicals
1. Aldcarb 100 kg. 116-06-3
2. 4-Adminidipheny 1 kg. 32-67-1
3. Amltom 1 kg 78-53-5
4. Anabasine 100 kg 494-52-0
5. Arsenic
pentoxide 500 kg
Arsenic
(v) acid & salts
6. Arsenic
trioxide Arsenious 100kg
(iii)acid &
salts
7. Lrsine
(Arsine(Arsinic 10 kg 7784-42-1
hydride)
8. Azinphos-ethy 100 kg 2642-71-9
9. Azinphos-methy 100 kg 86-50-0
10. Benzidine 1
kg 92-87-5
11. Benzkine Salts 1
kg
12. Beryllium(Powders, 10
kg
compounds)
13. Bis (2-chioroethyl) sulphide 1 kg 505-60-2
14. Bis (chioromethyl) ether 1
kg 542-88-1
15. Carbofiran 100
kg 1563-66-2
16. Carbophenthion 100
kg 786-19-6
17. Chlorfenvnphos 100
kg 470-90-6
18. 4-(chiorofomyl) Morpholine 1 kg 15159-40-7
19 Chotomethyl
ether 1 kg 107-30-2
20. Cobalt metal, oxides, 1
t
carbonates,
sulphides, as
powders
21. Crimidine 100
kg 535-89-7
22 Cyanthoate 100 kg 3734-95-0
23 Cylcheximide 100 kg 66-81-9
24 Demeton 100 kg 8065-48-3
25 Diallfos 100 kg 10311-84-9
26 co-diethyl 100 kg 2588-05-8
S-ethyisulphnylmethy
Phosphorothloate
27 co-Doethyl 100 kg 2588-06-9
S-ethyisulphonylmethyl
Phosphorothloate
28 co-Diethyl 100kg 2600-69-3
S-ethylthiomethys
Phosphorodithithioate
29
co-Diethyl 100
kg 78-52-4
S-isoprophyithiomethyl
Phosphorodithioate
30
co-Diethyl 100
kg 3309-68-0
S-propylthiomethyl
Phosphorothloate
31 Dimefox 100 kg 115-26-4
32 Dimethyyl carbamoyl 1 kg 79-44-7
chloride
33 DimethyInitosamine 1 kg 62-75-9
34 Dimethyl 1 t 63917-41-9
35 Diphacinone 100 kg 82-66-6
36 Disulfoton 100 kg 298-04-4
37 EPN 100 kg 2104-64-5
38 Ethion 100 kg 563-12-2
39 Fensulfothion 100 kg 115-90-2
40 Fluenetil 100 kg 4301-50-2
41 Fluoroacetic acid 1 kg 144-49-0
42 Fluoroacetic acid, salt 1 kg
43 Fluoroacetic acid, esters 1 kg
44 Fluoroacetic acid, amides 1 kg
45 4-Fluorobutyric acid 1 kg 462-23-7
46 4-Fluorobutyric acid, salts 1 kg
47 4-Fluorobutyric esters 1 kg
48 4-Fluorobutyric acid, amides 1 kg
49 4-Fluorocrotonic acid 1 kg 37759-72-1
50 4-Fluorocrotonic acid, salts 1 kg
51 4-Fluorocrotonic esters 1 kg
52 4-Fluorocrotonic acid, amide 1 kg
53 4-flouro-2-hydroxide-butyric 1 kg
acid
54 4-flouro-2-hydroxide-butyric 1 kg
acid,
salts
55 4-flouro-2-hydroxide-butyric 1 kg
acid,
esters
56 4-flouro-2-hydroxide-butyric 1 kg
acid,
amides
57 Glycolonitrile 100 kg 107-16-4
(hydroxvacetonitrille)
58 1,2,3,7,8,9- 100 kg 19408-74-3
Hexachiorodibenzo
p-dioxin
59 Hexamethyipho
sphoramide 1 kg 680-31-9
sphoramids
60 Hydrogen
selenid 10 kg 7783-07-5
61 Isobenzan 100 kg 297-78-9
62 Isodrin 100 kg 465-73-6
63 Juglone(5-Hydroxynapthe- 100 kg 481-39-0
lene-1,4-dione)
64 4,4’
–Methylenebls 10 kg 101-14-4
(2-chloroaniline)
65 Methy/Isocyanate 150 kg 150kg 624-83-9
66 Mevinphose 100 kg 7786-34-7
67 2-Naphhthylamine 1 kg 31-59-8
68 Nichel
metal, Oxides, 1 t 31-59-8
carbonates,
sulphide, as
powders
69 Nickel
tetracarbony 10 kg 13463-39-3
70 Oxydisulfoton 100 kg 2497-07-6
71 Oxygen
diffuoride 10 kg 7783-41-7
72 Paraoxon(diethyl) 100 kg 311-45-5
4-nitrophenyl(Phosphate)
73 Parathion 100 kg 56-38-2
74 Parathion-methyl 100 kg 298-00-0
75 Pentaborane 100 kg 19624-22-7
76 Phorate 100 kg 298-02-2
77 Phosacetion 100 kg 4104-14-7
78 Phosgene
(cabony) chloride 750 kg 750 kg 75-44-5
79 Phosphamidon 100 kg 13171-21-6
80 Phosphine
(hydrogen 100 kg 7803-51-2
phosphide)
81 Promurit(1-(3,4-Dichoroph- 100 kg 5836-73-7
enyl)-3triazenethio
caribox-
aamide)
82 1,3-Propanesuiltone 1 kg 1120-71-4
83 1-Propen-2
chioro-1,3-diol 10 kg 10118-72—6
diacetate
84 Pyrazoxon 100 kg 108-34-9
85 Seleniumhexaffuride 10 kg 7783-79-1
86 Sodium
selenite 100 kg 10102-18-8
87 Stabine(Antimony
hydride) 100 kg 7803-52-3
88 Sulfotop 100 kg 3689-24-5
89 Sulphur
dichloride 1 t 10545-99-0
90 Tellurium
hexafluoride 100 kg 7783-80-4
91 TEPP 100 kg 107-49-3
92 2,3,7,8-‘Tetrachlorodibenzo 1 kg 1746-01-6
P-dioxin
(TcDD)
93 Tetramethylenedisul- 1 kg 80-12-6
photetramine
94 Thionazin 100 kg 297-37-2
95 Tirpate
(2,4-Dimethyl 100 kg 26419-73-8
1,3-dithiolane
2-carboxaldehyde
0-methyl
carbomoyloxime)
96 Trichlormethane
Sulphenyl 100 kg 594-42-3
97 l-Tri(cyclohexyl)
stannyl- 100 kg 41083-11-8
1H-1.2,4-triazole
98 triethienmelamine 10 kg 51-18-3
99 Wartatin 100 kg 81-81-2
Group-2 –
Toxic Chemicals
(Quantity 1
tonne)
100 Acentone cyanohydrain 200 t 75-86-5
(2-cynopropan-2-01)
101 Acroieln(2-Propenal) 20 t 107-02-8
102 Acrylonitrelle 20 t 200t 107-13-1
103 Allyl alcohol (2-Propen-1-01) 200 t 107-18-6
104 Allylaine 200 t 107-11-9
105 Ammonia 50 t 500 t 7664-41-7
106 Bromine 40 t 7726-95-6
107 Carbon disulphide 20 t 200 t 75-15-0
108 Chlorine 10 t 25 t 7782-50-5
109 Diphyenl methane 20 t 101-68-8
di-isocyanate (MDI)
110 Ethylene dibromide 5 t 106-93-4
(1,2-Dibromomethane)
111 Ethyienelmine 50 t 151-56-4
112 Formaldehyde 5 t 50-00-0
(Concentration = 90%)
113 Hydrogen chloride (liquefied 25 t 250
t 7647-01-0
gas)
114 Hydrogen Cyanide 5 t 20 t 74-90-8
115 Hydrogen fluoride 5 t 50 t 7664-39-3
116 Hydrogen sulphide 5 t 50 t 7783-06-4
117 Methyl bromide 20 t 74-83-9
(Bromomethane)
118 Nitrogen oxides 50 t 11104-93-1
119 Propeyleneimine 50 t 75-55-8
120 Sulphur dioxide 20 t 250 t 7446-09-5
121 Sulphur trioxide 15 t 75 t 7446-11-9
122 Tetraethyl lead 5 t 78-00-2
123 Tetramethyl lead 5 t 75-74-1
124 Toluene di-isocyanate(TDI) 10 t 588-84-9
Group 3 – Highly Reactive Chemicals
125 Acentylene
(ethyne) 5 t 74-86-2
126 a. Ammonium nitrate (1) 350 t 2500
t 6484-52-2
b. Ammonium
nitrate in the 1,250 t
form
of fertilizer (2)
127 2,2
Bis (tert-butyl peroxy) 5 t 2167-23-9
butane (concentration >=70%)
128 1,1
Bis (tert-butyl peroxy) 5 t 3006-86-8
cyclohexane
(concentration
>=80%)
129 Tert-Butyl peroxyacetate 5 t 107-71-1
(concentration >=70%)
130 Tert-Butyl peroxysobutyrate 5 t 109-13-7
(concentration >=80%)
131 Tert-Butyl peroxyisopropl 5 t 2372-21-6
carbonate (concentration
>=80%)
132 Tert-Butyl peroxymaleate 5 t 1931-62-0
concentration >=80%)
133 Tert-Butyl peroxypivalate 50 t 927-07-1
(concentration >=77%)
134 Dibenzyl peroxydicarbinate 5 t 2144-45-8
(concentration >=90%)
135 Did-sec-butyl peroxydicar- 5 t 19910-65-7
bonat(concentration >=80%)
136 Diethyl Peroxydicarbonate 50 t 14666-78-5
(concentration >=30%)
137 2,2-Dihydroperoxyoropana 5 t 2614-76-8
(concentration >=30%)
138 DI-Isobutryl peroxide 50 t 3437-84-1
(concentration >=50%)
139 Di-n-propyl peroxydlcarbo- 5 t 16066-38-9
nate (concentration
>=80%)
140 Ethylene oxide 5 t 50 t 75-21-8
141 Ethyl nitrate 50 t 625-58-1
142 3,3,6,6,9,9-Hexamethyl 50 t 22397-33-7
-1,2,4,5-tetroxacyclonane
(concentration >=75%)
143 Hydrogen 2 t 50 t 1333-74-0
144 Liquid oxygen 200 t 7782-44-7
145 Methyl ethyl ketone Peroxide 5 t 1338-23-4
(concentration >=60%)
146 Methyl isobutyl ketone 50 t 37206-20-5
peroxide (concentration
>=60%)
147 Peracetic acid 50 t 79-21-0
(concentration >=60%)
148 Propylene oxide 5 t 75-56-9
149 Sodium
chlorate 25 t 7775-09-9
Group – 4
Explosive Chemical
150 Barium azide 50 t 18810-58-7
151-Bis(2,4,6-trinito
phemy) 50 t 131-73-7
amine
152 Chiorotrinitribenzene 50 t 28260-61-9
153 Cellulose nitrate (containing 50 t 9004-70-0
>12.6 % nitrogen)
154 Cyclotetramethylene 50 t 2691-41-0
tetranitramine
155 Cyclotrimethylenetri 50 t 121-82-4
nitroamine
156 Diazodinitrophenol 10 t 7008-81-3
157 Diethylene glycol dinitete 10 t 693-21-0
158 Dinitrophenol, salts 50 t
159 Ethylene glycol dinitrate 10 t 628-96-6
160 1-Guanyl-4-nitrosamineo- 10 t 109-27-3
guanlu-1-tetrazene
161 2.2’,4.4’,6.6’ - 50 t 20062-22-0
Hexanitrostilbene
162 Hydrazine nitrate 50 t 13464-97-6
163 Lead azide 50 t 13424-46-9
164 Lead
styphnate (lead 2,4,6 50 t 15245-44-0
-trinitroresorcinoxide
165 Mercury
fulminate 10 t 628-86-4
166 N-Methyl-N,2,4,6 50 t 479-45-8
Tetranitroanline
167 Nitrogylcerine 10 t 10 t 55-63-0
168 Pentacrythritol tetranitrate 50 t 78-11-5
169 Picric acid- 2,4,6 50 t 88-89-1
(Trinitrophenol)
170 Sodium Picramate 50 t 831-52-7
171 Styphnic acid 50 t 82-71-3
(2,4,6-Trinitroresorcinol)
172 1,3,5-Triamino- 50 t 3058-38-6
2,4,6-Trinitrobenezene
173 Trinitroaniline 50 t 26952-42-1
174 2,4,6-Trinitroaniline 50 t 606-35-9
175 Trinitrobenzene 50 t 25377-32-6
176 Trinitrobenzoic acid 50 t 35860-50-5
177 Trinitrocresol 50 t 28905-71-7
178 2,4,6-trinitrophenetole 50 t 4732-14-3
179 2,4,6-Trinitrotoluene 50 t 50 t 118-96-7
SCHEDULE 4
(See rule 68-j (1) (b) (I), 1 (c))
Industrial
Installation within the meaning of sub-rule 1 (b)(I)
1.
installation for the production,
Processing for treatment of organic or inorganic chemicals using for this
purpose, among others :
a.
alkylation
b.
amlnation by amonolysis
c.
carbonylation
d.
condensation
e.
dehydrogenation
f.
esterification
g.
halogenation & manufacture
of halogens
h.
hydrogenation
i.
hydrolysis
j.
oxidation
k.
polymarization
l.
sulphmarization
m.
desulphurization, manufacture
and transformation of sulpher containing compounds
n.
nitration and manufacture of
nitrogen containing compounds
o.
manufacture of phosphorous
containing compounds
p.
formulation of pesticides and of
phamacetial products – pesticides
q.
distillation
r.
extracting
s.
solvation
t.
mixing
2.
Installation for distillation,
refining or other processing of petroleum or petroleum products.
3.
Installations for the total or
partial disposal of solid or liquid chemicals by incheration or chemical
decomposition.
4.
Installation for the production,
processing, or treatment of energy goses for example, LPG,LNG,SNG.
5.
Installation for the dry distillation
of coal or lignite.
6.
Installation for the production of
metals or non-metals by a wet process or by means of electrical energy.
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