Wednesday 9 January 2013

Characteristics and global warming/cooling effects of atmospheric aerosols



Characteristics and global warming/cooling effects
of atmospheric aerosols

M. Kasahara*, R. Höller, S. Tohno and Y. Ohnishi
Graduate School of Energy Science, Kyoto University,
Uji, Kyoto 611-0011, Japan
Tel: (81 77) 438 4408  Fax: (81 77) 438 4411  Email : kasahara@energy.kyoto-u.ac.jp


ABSTRACT

Last one decade, the importance of global environmental problems such as global warming and acid rain has been recognized at the worldwide. Atmospheric aerosols play an important role in such global environmental problems as well as the local air pollution problem. The grasp of physical and chemical properties of aerosol particles is essential to make clear the behavior of aerosols in the atmosphere and also their effects on human health and atmospheric environment.

In this paper, the characteristics of atmospheric aerosols and the effects of aerosols on the atmospheric environment, especially on global warming/cooling effect, are discussed.

Characteristics and environmental effects of
atmospheric aerosols

The properties of aerosol particles are described by a number of physical and chemical factors such as particle size, concentration, chemical component, density, optical property, reactivity, etc. And the most important factors are generally the concentration, particle size and chemical composition. The physical and chemical properties of atmospheric aerosols depend on their sources and scavenging mechanisms.

After aerosol particles are emitted from various kinds of natural and anthropogenic sources, they are transported by wind and dispersed. The properties of aerosols are changed by physical and chemical reactions during the transportation. Gas-to-particle conversion including the cloud formation is very important processes in aerosol behavior. The cloud formation is closely related to the global warming/cooling and acid rain problems.

Characterization of atmospheric aerosols

In order to characterize the atmospheric aerosols, the atmospheric aerosols were collected using a Low Pressure Cascade impactor. The LPC impactor can classify the particles between about 0.01 and 30 micrometer into 13 size ranges. The elemental concentrations of collected particles were measured by the PIXE analysis. Figure 1 shows the typical size distribution of the total mass, S and Fe elements. The thin solid line, thin broken line and thick solid line mean the insoluble component, soluble component and sum of them, respectively. The particle size distribution was grouped into three types. The first type shown typically in S, Zn and Pb size distribution skewed to the smaller size range and had only one peak in the fine particle region. The second type shown in Si, Ca, Fe and Ti skewed to the larger size range and had nearly one peak in the coarse particle region. The third type was the bimodal distribution with one peak each in fine and coarse fractions and the distributions of the total mass, K, V, Mn and Cu were represented by this type.
 
 








Figure 1. Particle size distribution of total mass, S and Fe: Thin solid line = insoluble component;
Thin broken line = soluble component; and Thick solid line = total.

Global warming/cooling effects of atmospheric aerosols

The atmospheric aerosols influence on global warming in two ways. One is direct effect by absorbing and scattering the radiation. The other is indirect effect through the cloud formation. The effects of aerosols on the global warming/cooling depend on their physical and chemical properties, especially the amount of elemental carbon (EC).



Figure 2.  Chemical composition of fine mode aerosols.
 in Kyoto and Nagoya area.
 
 
       Figure 3.  Aerosol radiative forcing and single scattering.
albedo estimated in Kyoto and Nagoya.
 
The simultaneous measurements of solar radiation and physical and chemical properties of aerosol particles were carried out in Kyoto and other cities in Japan to study the effects of atmospheric aerosols on the global warming/ cooling. Figures 2 and 3 show an example of chemical composition of atmospheric fine mode aerosols and the aerosol radiation forcing calculated for the measurement data   in Kyoto and Nagoya. The values of aerosol radiation forcing in Kyoto ranged between –5.3 and +3.5w/m2 with the average of –1.5w/m2 that indicated cooling effect. On the other hand, the radiation forcing in Nagoya was estimated from +0.55 to +9.0 w/m2 with average of +3.3 w/m2 indicating warming effects. The difference in the effects of aerosols in both cities may be caused by the big difference in EC concentration.


Acknowledgements


A part of this work has been done under the program of the Research for the Future (RFTF) of the Japan Society for the Promotion of Science (JSPS- RFTF97P01002) and Grant-in-Aid for Scientific Research (B) under Grant No. 09044161 from Ministry of Education, Science, Sports and Culture, Japan.

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