Friday, 1 August 2025

Solar panels convert sunlight into electricity through the photovoltaic effect, a process in volving both the chemistry and physics of semiconductors.

 Solar panels convert sunlight into electricity through the photovoltaic effect, a process involving both the chemistry and physics of semiconductors. Sunlight, composed of photons, strikes a solar cell (typically made of silicon) and excites electrons, causing them to flow and generate an electrical current. 

Here's a more detailed breakdown:

1. Chemistry of Semiconductors:

Solar cells are primarily made of semiconductors like silicon. Silicon, with four valence electrons, forms covalent bonds with neighboring silicon atoms. 

To create a p-type semiconductor, impurities like boron (with three valence electrons) are added. This creates "holes" (vacancies where electrons should be) which act as positive charge carriers. 

For an n-type semiconductor, impurities like phosphorus (with five valence electrons) are added. This creates free electrons, which act as negative charge carriers. 

When a p-type and n-type semiconductor are joined, electrons from the n-type material move to fill the holes in the p-type material, creating a depletion region and an internal electric field. 

2. Physics of the Photovoltaic Effect:

Photon Absorption:

When sunlight (photons) strikes the solar cell, photons with energy greater than the band gap of the semiconductor are absorbed. 

Electron Excitation:

The absorbed photon energy excites electrons, freeing them from their covalent bonds and allowing them to move through the material. 

Current Generation:

The internal electric field within the depletion region forces these free electrons to flow in a specific direction, creating a direct current (DC). 

External Circuit:

When the solar cell is connected to an external circuit, this DC current can flow through it, powering devices. 

Inverters:

In most applications, this DC electricity is then converted to alternating current (AC) by an inverter, which is the standard form of electricity used in homes and businesses. 

3. Key Concepts:

Band Gap:

The minimum energy required for an electron to jump from the valence band to the conduction band and become free, according to Wikipedia. The band gap of silicon is 1.12 eV. 

Electron-Hole Pairs:

The process of photon absorption creates electron-hole pairs. The electron moves to the n-type side, and the hole moves to the p-type side. 

Doping:

The process of adding impurities to a semiconductor to change its electrical properties, according to ScienceDirect.com. 

Photovoltaic Cell - GeeksforGeeks

In essence, solar panels harness the power of photons to create a flow of electrons, which can be use

d to generate electricity. 

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