Saturday 21 July 2012

"Hazardous Chemical"

"Hazardous Chemical" means any chemical which is of the criteria specified in part I of Schedule I and is included in the list of column (2) of part II of that Schedule, or any chemical included in the list in Column 2 of Schedule 2; or any chemical included in the list of Column 2 of Schedule 3; and. "Industrial activity" means any operation or process carried out in an industrial installation referred to in Schedule 4 involving or likely to involve one or more hazardous chemicals and includes on site storage or on-site transport which is associated with that operation or process as the case may be; or isolated storage and
"Isolated Storage" means storage where no other manufacturing process than pumping of hazardous chemical is carried out and that storage involves at least the quantity of that chemical set out in Schedule 2, but does not include storage associated with an installation specified in schedule 4 on the same site;

 
SCHEDULE I
(SEE RULE 68 – j(1)(a)(i), (2)(1), (3)(1)(a)
INDICATIVE CRITERIA AND LIST OF CHEMICALS
PART I - INDICATIVE CRITERIA
(a)    Toxic Chemicals:

Chemicals having the following values of acute toxicity and which owing to their physical and chemical properties, are capable of producing major accident hazards:
Sr.No.
Degree of toxicity
LD50 Absorbed orally in rats mg/kg body weight


















Sr.No. Degree of Medium lethal Medium lethal Medium
Toxicity dose by the dose by the lethal
oral route dermal route concentr-
toxicity) (dermal LD50 ation by
LD50 (mg/kg body weight inhalation
body weight of test route(Four
of test ani- animals) hours)LC50
mals) (mg/1 inh-
alation in
test ani-
mals)
___________________________________________________________
1. Extremely 1-50 1-200 0.1 - 0.5
toxic


2. Highly 51-500 201-2000 0.5 - 2.0
toxic
__________________________________________________________
1.       Flammable Chemicals:
1.       flammable gases ; chemicals which in the gascous state at normal pressure and mixed with air become flammable and the boiling point of which at normal pressure is 20 C or below;
2.       Highly flammable liquids; chemicals which have a flash point lower than 23 C and the boiling point of which at normal pressure is above 20 C;
3.       flammable liquids: chemicals which have a flash point lower than 65 C and which remain liquids under pressure, where particular processing conditions, such as high pressure and high temperature, may create major accident hazards.
2.       Explosives: chemicals which may explode under the effect of flame, heat or photo-chemical conditions or which are more sensitive to shocks or friction than dinitrobenzene.
PART II LIST OF HAZARDOUS AND TOXIC CHEMICALS


Sl.No. Name of the Chemical
1. 2.
1. Acetone
2. Acetone Cyanohydrine
3. Acetyl Chloride
4. Acetylene (Ethyne)
5. Acrolein (2-Propenal)
6. Acrylonitrile
7. Aldicarb
8. Aldrin
9. Alkyl Phthalate
10. Allyl Alcohol
11. Allylamine
12. Alpha Naphthyl Thiourea (Autu)
13. Aminodiphenyl, -4
14. Aminophenol-2
15. Amiton
16. Ammonia
17. Ammonium Nitrate
18. Ammonium Nitrates in fertilizers
19. Ammonium Sulfamate
20. Anabasine
21. Aniline
22. Anisidine-p
23. Antimony and Compounds
24. Antimony Hydride (Stibine)
25. Arsenic Hydride (Arsine)
26. Arsenic Pentoxide, (Arsenic)(v) Acid and Salts
27. Arsenic Trioxide, Arsenious (iii) Acids and Salts
28. Asbestos
29. Azinphos-Ethyl
30. Azinphos-Methyl
31. Barium Azide
32. Benzene
33. Benzidine
34. Benzidine Salts
35. Benzoquinone
36. Benzoyl Chloride
37. Benzoyl Peroxide
38. Benzyl Chloride
39. Benzyl Cyanide
40. Beryllium (Powders, Compunds)
41. Biphenyl
42. Bis (2-Chloromethyl) Ketone
43. Bis (2, 4, 6-Trinitrophenyl) Amine
44. Bis (2-Chloroethyl) Sulphide
45. Bis (Chloromethyl) ketone
46. Bis (tert-Butylperoxy) Butane, -2, 2
47. Bis (tert-Butylperoxy) Cyclohexane, 11,
48. Bis, 1, 2 Tribromophenoxy-Ethane
49. Bisphenol
50. Boron and Compunds
51. Bromine
52. Bromine Pentafluoride
53. Bromoform
54. Butadiene-1, 3
55. Butane
57. Butanone-2
58. Butoxy Ethanol
59. ButylGlycidal Ether
60. Butyl Peroxyacetate, tert
61. Butyl peroxyisobutyrate, tert
62. Butyl peroxy isopropye carbonate, tert
63. Butyl Peroxymaleate, tert
64. Butyl Peroxypivalate, -tert
65. Butyl vinyl Ether
66. Butyl-n-Mercaptan
67. Butylamine
68. C 9-Aromatic Hydrocarbon Fraction
69. Cadmium and Compounds
70.
Cadmium Oxide (fumes)
71. Calcium Cyanide
72. Captan
73. Captofol
74. Carbaryl (Sevin)
75. Carbofuran
76. Carbon Disulphide
77. Carbon Monoxide
78. Carbon Tetrachloride
79.
Carbophenothion
80. Cellulose Nitrate
81. Chlorates (used in explosives)
82. Chlordane
83. Chlorfenvinphos
84. Chlorinated Benzenes
85. Chlorine
86. Chlorine Dioxide
87. Chlorine Oxide
88. Chlorine Trifluoride
89. Chlormequat Chloride
90. Chloroacetal Chloride
91. Chloroacetaldehyde
92. Chloroaniline, -2
93. Chloroaniline, -4
94. Chlorobenzene
95. Chlorodiphenyl
96. Chloroepoxypropane
97. Chloroethanol
98. Chloroethyl Chloroformate
99. Chlorofluorocarbons
100. Chloroform
101. Chloroformyl, -4, Morpholine
102. Chloromethane
103. Chloromethyl Ether
104. Chloromethyl Methyl Ether
105. Chloronitrobenzene
106. Chloroprene
107. Chlorosulphonic Acid
108. Chlorotrinitrobenzene
109. Chloroxuron
110. Chromium and Compounds
111. Cobalt and Compounds
112. Copper and Compounds
113. Coumafuryl
114. Comaphos
115. Coumatetralyl
116. Cresols
117. Crimidine
118. Cumene
119. Cyanophos
120. Cyanothoate
121. Cyanuric Fluoride
122. Cyclohexane
123. Cyclohexanol
124. Cyclohexanone
125. Cycloheximide
126. Cyclopentadiene
127. Cyclopentane
128. Cyclotetramethylentetranitramine
129. Cyclotrimethylene Trinitramine
130. DDT
131. Decabromodiphenyl Oxide
132. Demeton
133. Di-Isobutyl Peroxide
134. Di-n-propyl Peroxydicarbonate
135. Di-sec-Butyl Peroxydicarbonate
136. Dialifos
137. Diazodinitrophenol
138. Diazomethane
139. Dibenzyl Peroxydicarbonate
140. Dichloroacetylene-O
141. Dichloroobenzene-O
142. Dichlorobenzene-P
143. Dichloroethane
144. Dichloroethyl Ether
145. Dichlorophenol, -2, 4
146. Dichlorophenol, -2, 6
147. Dichlorophenoxy Acetic Acid, -2, 4(2, 4-D)
148. Dichloropropane, -1,2
149. Dichlorosalicylic Acid, -3, 5
150. Dichlorvos (DDVP)
151. Dicrotophos
152. Dieldrin
153. Diepoxybutane
154. Diethyl Peroxydicarbonate
155. Diethylene Glycol Dinitrate
156. Diethylene Triamine
157. Diethyleneglycol Butyl Ether/Diethyleneglycol
Butyl Acetate
158. Diethylenetriamine (DETA)
159. Diglycidyl Either
160. Dithydroperoxypropane, -2, 2
161. Di-isobutyryl Peroxide
162. Dimefox
163. Dimethoate
164. Dimethyl Phosphoramidocyanidic Acid
165. Dimethyl Phthalate
166. Dimethylcarbomyl
167. Dimethylnitrosamine
168. Dinitrophenol, Salts
169. Dinitrotoluene
170. Dintro-o-Cresol
171. Dioxane
172. Dioxathion
173. Dioxolane
174. Diphacinone
175. Diphosphoramide Octamethyl
176. Dipropylene Glycolmethylether
177. Disulfoton
178. Endosulfan
179. Endrin
180. Epichlorohydrine
181. EPN
182. Epoxypropane, 1, 2
183. Ethion
184. Ethyl Carbamate
185. Ethyl Ether
186. Ethyl Hexanol,-2
187.
Ethyl Mercaptan
188. Ethyl Methacrylate
189. Ethyl Nitrate
190. Ethylamine
191. Ethylene
192. Ethylene Chlorohydrine
193. Ethylene Diamine
194. Ethylene Dibromide
195. Ethylene Dichloride
196. Ethylene Glycol Dinitrate
197. Ethylene Oxide
198. Ethyleneimine
199. Ethylthiocyanate
200.
Fensulphothion
201. Fluenetil
202. Fluoro,-4, -2-Hydroxybutyrix Acid and Salts
Esters, Amides
203. Fluoracetic Acid and Salts, Esters, Amides
204. Fluorobutyric Acid, -4, and Salts,
Esters, Amides
205. Fluorocortonic Acid, -4, Salts, Esters,
Amides
206. Formaldehyde
207. Glyconitrile (Hydroxyacetonitrile)
208. Guanyl,-1, -4-Nitrosaminoguanyl-1-Tetrazene
209. Heptachlor
210. Hexachloro Cyclopentadiene
211. Hexachlorocyclohexane
212. Hexachlorocyclomethane
213. Hexachlorodibenzo-p-Dioxin, 1,2,3,7,8,9
214. Hexafluoropropene
215. Hexamethylphosphoramide
216. Hexamethyl, -3, 3, 6, 9, 9-1, 2, 4,
5-Tetraoxacyclononane
217. Hexamethylendiamine
218. Hexane
219. Hexanitrostilbene, -2, 2, 4, 4, 6, 6
220. Hexavalent Chromium
221. Hydrazine
222. Hydrazine Nitrate
223. Hydrochloric Acid
224. Hydrogen
225. Hydrogen Bromide (Hydrobromic Acid)
226. Hydrogen Chloride (Liquified Gas)
227. Hydrogen Cyanide
228. Hydrogen Fluoride
229. Hydrogen Selenide
230. Hydrogen Sulphide
231. Hydroquinone
232. Iodine
233. Isobenzan
234. Isodrin
235. Isophorone Diissocyanate
236. Isopropyl Ether
237. Juglone (5-Hydroxynaphthalene-1, 4-Dione)
238. Lead (inorganic fumes & dusts)
239. Lead 2, 4, 6-Trinitroresorcinoxide (Lead Styphnate)
240. Lead Azide
241. Leptophos
242. Lindane
243. Liquified Petroleum Gas (LPG)
244. Maleic Anhydride
245. Managanese & Compounds
246. Mercapto Benzothiazole
247. Mercury Alkyl
248. Mercury Fulminate
249. Mercury Methyl
250. Methacrylic Anhydride
251. Methacrylonitrile
252. Methacryloyl Chloride
253. Methamidophos
254. Methanesuphonyl Fluoride
255. Methanthiol
256. Methoxy Ethanol (2-Methyl Cellosolve)
257. Methoxycthylmercuric Acetate
258. Methyl Acrylate
269. Methyl Alcohol
260. Methyl Amylketone
261. Methyl Bromide (Bromomethane)
262. Methyl Chloride
263. Methyl Chloroform
264. Methyl Cyclohexene
265. Methyl ethyl Ketone Peroxide
266. Methyl Hydrazine
267. Methyl Isobutyl Ketone
268. Methyl Isobutyl Ketone Peroxide
269. Methyl Isocyanate
270. Methyl Isothiocyanate
271. Methyl Mercaptan
272. Methyl Methacrylate
273. Methyl Parathion
274. Methyl Phosphonic Dichloride
275. Mehtyl-N, 2, 4, 6-Tetranitroaniline
276. Methylene Chloride
277. Methylenebis, -4, 4, (2, -chloroanilne)
278. Methyltrichlorosilane
279. Mevinphos
280. Molybdenum & Compounds
281. N-Methyl-N, 2, 4, 6-Tetranitroanaline
282. Naphtha (Coal Tar)
283. Naphtylamine, 2
284. Nickel & Compounds
285. Nickel Tetracarbonyl
286. Nitroaniline-O
287. Nitroaniline-P
288. Nitrobenzene
289. Nitrochlorobenzene-P
290. Nitrocyclohexane
291. Nitroethane
292. Nitrogen Dioxide
293. Nitrogen Oxides
294. Nitrogen Trifluoride
295. Nitroglycerine
296. Nitrophenol-P
297. Nitropropane-1
298. Nitropropane-2
299. Nitrosodimethylamine
300. Nitrotoluene
301. Octabromophenyl Oxide
302. Oleum
303. Oleylamine
304. OO-Diethyl S-Ethysulphonlmethyl
305. OO-Diethyl S-Ethylsulphonylmethyl
Phosphorothioate
306. OO-Diethyl S-Ethylthiomethyl Phosphe rothioate
307. OO-Diethyl S-Isopropylthiomethyl
Phosphorodithioate
308. OO-Diethyl S-propylthiomethyl
Phophorodithioate
309. Oxyamyl
310. Oxydisulfoton
311. Oxygen (liquid)
312. Oxygen Difluoride
313. Ozone
314. Paroxon (diethyl 4-Nitrophenyl Phosphate)
315. Paraquat
316. Parathion
317. Parathion Methyl
318. Paris green (Bis Aceto Hexametarsen ito
Tetracopper)
319. pentaborane
320. Pentabromodiphenyl Oxide
321. Pentabromophenol
322. Pentachloro Naphthalene
323. Pentachloroethane
324. Pentachlorophenol
325. Pentaerythritol Tetranitrate
326. Pentane
327. Peracetic Acid
328. Perchloroethylene
329. Perchloromethyl Mercaptan
330. Petanone, 2, 4-Methyl
331. Phenol
332. Phenyl Glycidal Ether
333. Phenylene p-Diamine
334. Phenylmercury Acetate
335. Phorate
336. Phosacetim
337. Phosalone
338. Phosfolan
339. Phosgene (carbonyl chloride)
340. Phosmet
341. Phosphamidon
342. Phosphine (Hydrogen Phosphide)
343. Phosphoric Acid and Esters
344. Phosphoric Acid, Bromoethyl Bromo
(2, 2-Dimethylpropyl) Bromoethyl Ester
345. Phosphoric Acid, Bromoethyl Bromo
(2,2-Dimethylpropyl) Chloroethyl Ester
346. Phosphoric Acid Chloroethyl Bromo
(2,2-Dimethoxylpropyl Chloroethylester)

347. Phosphorous & Compounds
348. Phostalan
349. Picric Acid (2,4, 6-Trinitrophenol)
350. Polybrominated Biphenyls
351. Potassium Arsenite
352. Potassium Chlorate
353. Promurit (1-(3, 4-Dichlorophenyl)-
3 Triazenethiocarboxamide)
354. Propanesultone-1, 3
355. Propen-1, -2-Chloro-1, 3-Diol-Diacetate
356. Propylene Oixde
357. Propyleneimine
358. Pryazoxon
359. Selenium Hexafluoride
360. Semicarbazide Hydrochloride
361. Sodium Arsenite
362. Sodium Azide
363. Sodium Chlorate
364. Sodium Cyanide
365. Sodium Picramate
366. Sodium Selenite
367. Styrene, 1, 1, 3, 2-Tetrachloroethane
368. Sulfotep
369. Sulphur dichloride
370. Sulphur Dioxide
371. Sulphur Trioxide
372. Sulphuric Acid
373. Sulphoxide, 3-Chloropropyloctyl
374. Tellurium
375. Tellurium Hexafluoride
376. Tepp
377. Terbufos
378. Tetrabromobisphenol-A
379. Tetrachloro, 2, 2, 5,6,2, 5-Cyclohexadiene-1,
4-Dione
380. Tetrachlorodibenzo-p Dloxin, 2,3,7,8 (TCDD)
381. Tetraethyl Lead
382. Tetrafluoroethane
383. Tetramethylenedisulphotetramine
384. Tetramethyl Lead
385. Tetranitromethane
386. Thallium & Compounds
387. Thionazin
388. Thionazin
389. Thinoyl Chloride
389. Tirpate
390. Toluene
391. Toluene-2-4-Diicocyanate
392. Toluidine-O
393. Toluene 2,6-Diisocyanate
394. Trans-1, 4-Chlorobutene
395. Tri-1 (cyclohexyl) Stannyl-1H-1, 2, 4-Trazole
396. Triamino, -1, 3, 5, 2, 4, 6-Trintroxenzene
397. Tribromophenol, 2, 4, 6
398. Trichloro Acetyl Chloride
399. Trichloro Ethane
400. Trichloro Napthalene
401. Trichloro (Chloromethyl) Silane
402. Trichlorodichlorophenylsilane
403. Trichloroethane, 1,1, 1
404. Trichlorethyl Silane
405. Trichloroethylene
406. Trichloromethanesulphenyl Chloride
407. Trichlorophenol, 2, 2, 6
408. Trichloropnenol, 2, 4, 5
409. Triethylamine
410. Triethylenemelamine
411. Trimethyl Chlorosilane
412. Trimethylopropane Phosphite
413. Trinitroaniline
414. Trinitroanisole, 2, 2, 4, 6
415. Trinitrobenzene
416. Trinitrobenzoic Acid
417. Trinitrocresol
418. Trinitrophenetole, 2, 5, 6
419. Trinitroresorcinol, 2,4,6 (Styphnic Acid)
420. Trintrotoluene
421. Triothocresyl Phosphate
422. Triphenyltin Chloride
423. Turpentine
424. Uranium & Compounds
425. Vanadium & Compounds
426. Vinyl Chloride
427. Vinyl Fluoride
428. Vinyl Toluene
429. Warfarin
430. Xylene
431. Xylidine
432. Zinc & Compounds
433. Zirconium & Compounds
 
SCHEDULE 2

(See Rule 68-j-1(a) (ii),1(c),3(1)(b) and (5)(1)(c) and (d), 6(1)

ISOLATED STORAGE OF INSTALLANTION OTHER THAN THOSE

COVERED BY SCHEDULE 4.

(a)                 The quantities set out below relate to each installation or group of installations belonging to the occupier where the distance between installations is not sufficient to avoid, in foreseeable circumstances any aggravation of major accident hazards. These quantities apply in any case of each of the installations belonging to the same occupier where the distance between the installation is less than 500metres.
(b)                 For the purpose of determining the quantity of a hazardous chemical at an isolated storage, account shall also be taken of any hazardous chemical which is:

(i)                   in that part of any pipeline under the control of the occupier having control of the site, which is 500 meters of that site and connected to it.
(ii)                 at any other site under the control of the occupier any part of the boundary of which is 500 meters of the said site, and
(iii)                in any vehicle, vessel, aircraft or hovercraft or hovercraft under the control of the same occupier which is used for storage purpose either at the site or within 500metres of it.

but no account shall be taken of any hazardous chemical which is in a vehicle, vessel, aircraft or hovercraft for transporting it.

Sr
No.
Chemical or group of chemicals
Quantity
(tonnes)


For application of sub-Rules 3.5 and 6 to 8
For application of Sub-Rule6
(col.1)
(col.2)
(col.3) Tonnes
(col.4)
1.
Acryionitrile
350
5.000
2.
Ammonia
60
600
3.
Ammonium nitrate
350*
2500*
4.
Ammonium nitrate fertilizers
1,250
10,000
5.
Chlorine
10
25
6.
Flammable gases as defined in Schedule1, paragraph 1, paragraph (b)
50
300
7.
Highly flammable liquids as define in Schedule I paragraph(b)
10,000
10,000
8.
Liquid oxygen
200
2000
9.
Sodium chlorate
25
250
10.
Sulphur dioxide
20
500
11.
Sulphur trioxide
15
100

*Where this chemical is in a state which gives it properties capable of creating of creating a major accident hazard.

Footnotes-


(a)                 This applies to ammonium  nitrate and mixture of ammonium nitrate where the nitrogen content derived from the ammonium nitrate is greater than 28 per cent by weight and to aqueous solutions solutions of ammonium nitrate where the concentration of ammonium nitrate is greater than 90 per cent by weight.
(b)                 This applies to straight ammonium nitrate fertilizers and to compound fertilisers where the nitrogen content derived form the ammonium nitrate is greater than 28 per cent by weight (a compound fertilizer contains ammonium nitrate together with phosphate and/or potash.)   


 
SCHEDULE 3

(See Rules 68-J 1(a)(iii), 1(e) and (5)(1) and (b),6(1))

LIST OF HAZARDOUS CHAMICALS FOR APPLICATION OF SUB-RULES
5 AND 7 TO 13

(a)        The quantities set out below relate to installation or group of installations belonging to the same occupier where the distance between the installations is not sufficient to avoid in foreseeable circumstances, any aggravation of major accident hazards. These quantities apply in any case to each group of installation belonging to the same occupier where the distance between the installations is lass then 500 meters.
(b)        For the purpose of determining the quantity of control of a hazardous chemical in an industrial installation, account shall also be taken of any hazardous chemical which is:
     
(i)                  in that part of any pipeline under the control of the occupier having control of the site, which is within 500 meters of that site and connected to it;
(ii)                at any other site under the control of the same occupier any part of the boundary of which is within 500 meters of side; and
(iii)               in any vehicle, vessel, aircraft or hovercraft under the control of the same occupier which is used for storage purpose either at the site or within 500 meters of it.
But no account shall be taken of any hazardous chemical which is in a vehicle vessel, aircraft or hovercraft used for transporting it.






















SCHEDULES 3 (Continued)

PART 1 – NAMED CHAMICALS


Sr. No.       Chemical                                              Quantity                       CAS Number
                                                                  ____________________
                                                                  For                         For
                                                                  Application       application
                                                                  Of sub-rules     of sub-rules
                                                                  (4) (6) to (8)     9 to 11            
                                                                  and 12
(1)              (2)                                            (3)                    (4)                    (5)
                  Group 1 – Toxic Chemicals
1.               Aldcarb                                    100 kg.                                    116-06-3
2.               4-Adminidipheny                      1 kg.                                        32-67-1
3.               Amltom                                    1 kg                                         78-53-5
4.               Anabasine                                100 kg                                     494-52-0
5.               Arsenic pentoxide                     500 kg
                  Arsenic (v) acid & salts
6.               Arsenic trioxide Arsenious        100kg
(iii)acid & salts
7.               Lrsine (Arsine(Arsinic   10 kg                                       7784-42-1
                  hydride)                                   
8.               Azinphos-ethy                          100 kg                                     2642-71-9
9.               Azinphos-methy                        100 kg                                     86-50-0
10.             Benzidine                                  1 kg                                         92-87-5
11.             Benzkine Salts                          1 kg                                        
12.             Beryllium(Powders,                  10 kg
                  compounds)
13.             Bis (2-chioroethyl) sulphide       1 kg                                         505-60-2
14.             Bis (chioromethyl) ether            1 kg                                         542-88-1
15.             Carbofiran                                100 kg                                     1563-66-2
16.             Carbophenthion                        100 kg                                     786-19-6
17.             Chlorfenvnphos                        100 kg                                     470-90-6
18.             4-(chiorofomyl) Morpholine      1 kg                                         15159-40-7
19              Chotomethyl ether                    1 kg                                         107-30-2
20.             Cobalt metal, oxides,                1 t
                  carbonates, sulphides, as
                  powders
21.             Crimidine                                  100 kg                                     535-89-7
22              Cyanthoate                               100 kg                                     3734-95-0
23              Cylcheximide                            100 kg                                     66-81-9
24              Demeton                                  100 kg                                     8065-48-3
25              Diallfos                         100 kg                                     10311-84-9
26              co-diethyl                                 100 kg                                     2588-05-8
                  S-ethyisulphnylmethy
                  Phosphorothloate
27              co-Doethyl                               100 kg                                     2588-06-9
                  S-ethyisulphonylmethyl
                  Phosphorothloate
28              co-Diethyl                                100kg                                      2600-69-3
                  S-ethylthiomethys
                  Phosphorodithithioate
29                            co-Diethyl                                100 kg                                     78-52-4
S-isoprophyithiomethyl
Phosphorodithioate
30                            co-Diethyl                                100 kg                                     3309-68-0
S-propylthiomethyl
Phosphorothloate
      31              Dimefox                                   100 kg                                     115-26-4
      32              Dimethyyl carbamoyl                1 kg                                         79-44-7
                        chloride
      33              DimethyInitosamine                   1 kg                                         62-75-9
      34              Dimethyl                                   1 t                                            63917-41-9
      35              Diphacinone                             100 kg                                     82-66-6
      36              Disulfoton                                 100 kg                                     298-04-4
      37              EPN                                         100 kg                                     2104-64-5
      38              Ethion                                       100 kg                                     563-12-2
      39              Fensulfothion                            100 kg                                     115-90-2
      40              Fluenetil                                    100 kg                                     4301-50-2
      41              Fluoroacetic acid                      1 kg                                         144-49-0
      42              Fluoroacetic acid, salt               1 kg
      43              Fluoroacetic acid, esters           1 kg
      44              Fluoroacetic acid, amides          1 kg
      45              4-Fluorobutyric acid                 1 kg                                         462-23-7
      46              4-Fluorobutyric acid, salts         1 kg
      47              4-Fluorobutyric esters               1 kg
      48              4-Fluorobutyric acid, amides     1 kg                                                    
      49              4-Fluorocrotonic acid               1 kg                                         37759-72-1
      50              4-Fluorocrotonic acid, salts       1 kg
      51              4-Fluorocrotonic esters 1 kg
      52              4-Fluorocrotonic acid, amide    1 kg
      53              4-flouro-2-hydroxide-butyric    1 kg
                        acid
      54              4-flouro-2-hydroxide-butyric    1 kg
                        acid, salts
      55              4-flouro-2-hydroxide-butyric    1 kg
                        acid, esters
      56              4-flouro-2-hydroxide-butyric    1 kg
                        acid, amides

57                    Glycolonitrile                            100 kg                                     107-16-4
                        (hydroxvacetonitrille)
58                    1,2,3,7,8,9-                              100 kg                                     19408-74-3
                        Hexachiorodibenzo p-dioxin
59                    Hexamethyipho sphoramide      1 kg                                         680-31-9
                        sphoramids                              
60                    Hydrogen selenid                      10 kg                                       7783-07-5
61                    Isobenzan                                 100 kg                                     297-78-9
62                    Isodrin                                      100 kg                                     465-73-6
63                    Juglone(5-Hydroxynapthe-       100 kg                                     481-39-0
                        lene-1,4-dione)            
64                    4,4’ –Methylenebls                   10 kg                                       101-14-4
                        (2-chloroaniline)
65                    Methy/Isocyanate                     150 kg             150kg              624-83-9
66                    Mevinphose                              100 kg                                     7786-34-7
67                    2-Naphhthylamine                    1 kg                                         31-59-8
68                    Nichel metal, Oxides,                1 t                                            31-59-8
                        carbonates, sulphide, as
                        powders
69                    Nickel tetracarbony                  10 kg                                       13463-39-3
70                    Oxydisulfoton                           100 kg                                     2497-07-6
71                    Oxygen diffuoride                     10 kg                                       7783-41-7
72                    Paraoxon(diethyl)                     100 kg                                     311-45-5
                        4-nitrophenyl(Phosphate)
73                    Parathion                                  100 kg                                     56-38-2
74                    Parathion-methyl                       100 kg                                     298-00-0
75                    Pentaborane                             100 kg                                     19624-22-7
76                    Phorate                                    100 kg                                     298-02-2
77                    Phosacetion                              100 kg                                     4104-14-7
78                    Phosgene (cabony) chloride      750 kg             750 kg             75-44-5
79                    Phosphamidon                          100 kg                                     13171-21-6
80                    Phosphine (hydrogen                100 kg                                     7803-51-2
                        phosphide)      
81                    Promurit(1-(3,4-Dichoroph-     100 kg                                     5836-73-7
                        enyl)-3triazenethio caribox-
                        aamide)
82                    1,3-Propanesuiltone                  1 kg                                         1120-71-4
83                    1-Propen-2 chioro-1,3-diol      10 kg                                       10118-72—6
                        diacetate
84                    Pyrazoxon                                100 kg                                     108-34-9
85                    Seleniumhexaffuride                  10 kg                                       7783-79-1
86                    Sodium selenite             100 kg                                     10102-18-8
87                    Stabine(Antimony hydride)        100 kg                                     7803-52-3
88                    Sulfotop                                   100 kg                                     3689-24-5
89                    Sulphur dichloride                     1 t                                            10545-99-0
90                    Tellurium hexafluoride   100 kg                                     7783-80-4
91                    TEPP                                       100 kg                                     107-49-3
92                    2,3,7,8-‘Tetrachlorodibenzo     1 kg                                         1746-01-6
                        P-dioxin (TcDD)
93                    Tetramethylenedisul-                 1 kg                                         80-12-6
                        photetramine                
94                    Thionazin                                  100 kg                                     297-37-2
95                    Tirpate (2,4-Dimethyl               100 kg                                     26419-73-8
                        1,3-dithiolane 2-carboxaldehyde
                        0-methyl carbomoyloxime)
96                    Trichlormethane Sulphenyl        100 kg                                     594-42-3
97                    l-Tri(cyclohexyl) stannyl-           100 kg                                     41083-11-8
                        1H-1.2,4-triazole
98                    triethienmelamine                      10 kg                                       51-18-3
99                    Wartatin                                   100 kg                                     81-81-2
            Group-2 – Toxic Chemicals
            (Quantity 1 tonne)
100                  Acentone cyanohydrain 200 t                                        75-86-5
                        (2-cynopropan-2-01)
101                  Acroieln(2-Propenal)                20 t                                          107-02-8
102                  Acrylonitrelle                            20 t                  200t                 107-13-1
103                  Allyl alcohol (2-Propen-1-01)   200 t                                        107-18-6
104                  Allylaine                                   200 t                                        107-11-9
105                  Ammonia                                  50 t                  500 t                7664-41-7
106                  Bromine                                   40 t                                          7726-95-6
107                  Carbon disulphide                     20 t                  200 t                75-15-0
108                  Chlorine                                   10 t                  25 t                  7782-50-5
109                  Diphyenl methane                     20 t                                          101-68-8
                        di-isocyanate (MDI)
110                  Ethylene dibromide                   5 t                                            106-93-4
                        (1,2-Dibromomethane)
111                  Ethyienelmine                            50 t                                          151-56-4
112                  Formaldehyde                          5 t                                            50-00-0
                        (Concentration = 90%)
113                  Hydrogen chloride (liquefied     25 t                  250 t                7647-01-0
                        gas)
114                  Hydrogen Cyanide                    5 t                    20 t                  74-90-8
115                  Hydrogen fluoride                     5 t                    50 t                  7664-39-3
116                  Hydrogen sulphide                    5 t                    50 t                  7783-06-4
117                  Methyl bromide                        20 t                                          74-83-9
                        (Bromomethane)                      
118                  Nitrogen oxides                        50 t                                          11104-93-1
119                  Propeyleneimine                       50 t                                          75-55-8
120                  Sulphur dioxide                         20 t                  250 t                7446-09-5
121                  Sulphur trioxide                        15 t                  75 t                  7446-11-9
122                  Tetraethyl lead              5 t                                            78-00-2
123                  Tetramethyl lead                       5 t                                            75-74-1
124                  Toluene di-isocyanate(TDI)      10 t                                          588-84-9
Group 3 – Highly Reactive Chemicals
125                  Acentylene (ethyne)                  5 t                                            74-86-2
126                  a. Ammonium nitrate (1)           350 t                2500 t              6484-52-2
                        b. Ammonium nitrate in the        1,250 t
                        form of fertilizer (2)
127                  2,2 Bis (tert-butyl peroxy)         5 t                                            2167-23-9
                        butane (concentration >=70%)
128                  1,1 Bis (tert-butyl peroxy)         5 t                                            3006-86-8
                        cyclohexane (concentration
                        >=80%)
129                  Tert-Butyl peroxyacetate          5 t                                            107-71-1
                        (concentration >=70%)
130                  Tert-Butyl peroxysobutyrate    5 t                                            109-13-7
                        (concentration >=80%)
131                  Tert-Butyl peroxyisopropl         5 t                                            2372-21-6
                        carbonate (concentration
 >=80%)
132                  Tert-Butyl peroxymaleate          5 t                                            1931-62-0
                        concentration >=80%)
133                  Tert-Butyl peroxypivalate          50 t                                          927-07-1
                        (concentration >=77%)
134                  Dibenzyl peroxydicarbinate       5 t                                            2144-45-8
                        (concentration >=90%)
135                  Did-sec-butyl peroxydicar-       5 t                                            19910-65-7
bonat(concentration >=80%)
136                  Diethyl Peroxydicarbonate        50 t                                          14666-78-5
                        (concentration >=30%)
137                  2,2-Dihydroperoxyoropana      5 t                                            2614-76-8
                        (concentration >=30%)
138                  DI-Isobutryl peroxide               50 t                                          3437-84-1
                        (concentration >=50%)
139                  Di-n-propyl peroxydlcarbo-      5 t                                            16066-38-9
                        nate (concentration >=80%)
140                  Ethylene oxide              5 t                    50 t                  75-21-8
141                  Ethyl nitrate                              50 t                                          625-58-1
142                  3,3,6,6,9,9-Hexamethyl            50 t                                          22397-33-7
                        -1,2,4,5-tetroxacyclonane
                        (concentration >=75%)
143                  Hydrogen                                 2 t                    50 t                  1333-74-0
144                  Liquid oxygen                           200 t                                        7782-44-7
145                  Methyl ethyl ketone Peroxide    5 t                                            1338-23-4
                        (concentration >=60%)
146                  Methyl isobutyl ketone  50 t                                          37206-20-5
                        peroxide (concentration >=60%)
147                  Peracetic acid                           50 t                                          79-21-0
                        (concentration >=60%)
148                  Propylene oxide                        5 t                                            75-56-9
149                  Sodium chlorate                        25 t                                          7775-09-9
            Group – 4 Explosive Chemical
150                  Barium azide                             50 t                                          18810-58-7
                        151-Bis(2,4,6-trinito phemy)    50 t                                          131-73-7
                        amine
152                  Chiorotrinitribenzene                 50 t                                          28260-61-9
153                  Cellulose nitrate (containing       50 t                                          9004-70-0
                        >12.6 % nitrogen)
154                  Cyclotetramethylene                 50 t                                          2691-41-0
                        tetranitramine
155                  Cyclotrimethylenetri                  50 t                                          121-82-4
                        nitroamine
156                  Diazodinitrophenol                    10 t                                          7008-81-3
157                  Diethylene glycol dinitete           10 t                                          693-21-0
158                  Dinitrophenol, salts                   50 t                                         
159                  Ethylene glycol dinitrate 10 t                                          628-96-6
160                  1-Guanyl-4-nitrosamineo-         10 t                                          109-27-3
                        guanlu-1-tetrazene
161                  2.2’,4.4’,6.6’ -                         50 t                                          20062-22-0
                        Hexanitrostilbene                     
162                  Hydrazine nitrate                       50 t                                          13464-97-6
163                  Lead azide                                50 t                                          13424-46-9
164                  Lead styphnate (lead 2,4,6        50 t                                          15245-44-0
-trinitroresorcinoxide
165                  Mercury fulminate                     10 t                                          628-86-4
166                  N-Methyl-N,2,4,6                    50 t                                          479-45-8
                        Tetranitroanline
167                  Nitrogylcerine                           10 t                  10 t                  55-63-0
168                  Pentacrythritol tetranitrate         50 t                                          78-11-5
169                  Picric acid- 2,4,6                      50 t                                          88-89-1
                        (Trinitrophenol)
170                  Sodium Picramate                     50 t                                          831-52-7
171                  Styphnic acid                            50 t                                          82-71-3
                        (2,4,6-Trinitroresorcinol)
172                  1,3,5-Triamino-                        50 t                                          3058-38-6
                        2,4,6-Trinitrobenezene
173                  Trinitroaniline                            50 t                                          26952-42-1
174                  2,4,6-Trinitroaniline                  50 t                                          606-35-9
175                  Trinitrobenzene             50 t                                          25377-32-6
176                  Trinitrobenzoic acid                  50 t                                          35860-50-5
177                  Trinitrocresol                            50 t                                          28905-71-7
178                  2,4,6-trinitrophenetole              50 t                                          4732-14-3
179                  2,4,6-Trinitrotoluene                 50 t                  50 t                  118-96-7

 
SCHEDULE 4
(See rule 68-j (1) (b) (I), 1 (c))
Industrial Installation within the meaning of sub-rule 1 (b)(I)

1.                   installation for the production, Processing for treatment of organic or inorganic chemicals using for this purpose, among others :

a.                    alkylation
b.                   amlnation by amonolysis
c.                    carbonylation
d.                   condensation
e.                    dehydrogenation
f.                     esterification
g.                   halogenation & manufacture of halogens
h.                   hydrogenation
i.                     hydrolysis
j.                     oxidation
k.                    polymarization
l.                     sulphmarization

m.                  desulphurization, manufacture and transformation of sulpher containing compounds

n.                   nitration and manufacture of nitrogen containing compounds

o.                   manufacture of phosphorous containing compounds

p.                   formulation of pesticides and of phamacetial products – pesticides

q.                   distillation

r.                     extracting

s.                    solvation

t.                     mixing

2.                   Installation for distillation, refining or other processing of petroleum or petroleum products.
3.                   Installations for the total or partial disposal of solid or liquid chemicals by incheration or chemical decomposition.
4.                   Installation for the production, processing, or treatment of energy goses for example, LPG,LNG,SNG.
5.                   Installation for the dry distillation of coal or lignite.
6.                   Installation for the production of metals or non-metals by a wet process or by means of electrical energy.



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