What are the common chemical inhibitors used for water treatment?
The common chemical inhibitors compounds are:
1. Chromates: These are generally used with zinc
and poly-phosphates. When chromates are used alone, the level should be
maintained otherwise it would promote corrosion. Few countries/states do not
permit the use of chromates because of its toxic nature.
2. Poly-Phosphates: These basically extend the
solubility limit of Calcium. The main limitation of these are that in case pH
increases beyond 7.3, these will be converted into ortho-compound, which will
react with calcium and form the sludge.
3. Zinc: These provide film of zinc hydroxide. If
pH = 6.5, maintenance is must. If pH > 6.5, zinc will go to the solution. If
pH < 6.5, it will precipitate. It will tend to absorb the suspended
particulates, which shall lead to higher turbidity.
4. Nitrates:
These are anodic inhibitors. High level of sulphates and chlorides will
affect its performance that leads to high turbidity.
5.
Silicates:
This cannot be used if pH is high (> 7) and hardness is over 250 ppm.
6. Sodium Meta Phosphate (SHMP): This is
effective in a sense that it delays the solubility limit of calcium salts and
therefore the scale formation is delayed. The disadvantage however is that it
degenerates into ortho-compound and require pH to be controlled with in 6.5 to
7.4. It also acts as food for bio fouling. The latest developments are
employing Amino Trimithylene Phosphonate Acid (ATMP) and Hydroxyl Ethylkedene
di-Phosphonate Acid (HEDP) that does not have the limitations of SHMP.
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